Coordination polymers of 5-substituted
1,2,3,4-tetracyanocyclopentadienides: structural and
electrochemical properties of complex compounds of 5-amino- and
5-nitro-tetracyanocyclopentadienide

J 2021

Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide

NIMAX, Patrick René; Nils ROTTHOWE; Florian ZOLLER; Tobias BLOCKHAUS; Fritz WAGNER et. al.

Basic information

Original name

Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide

Authors

NIMAX, Patrick René; Nils ROTTHOWE; Florian ZOLLER; Tobias BLOCKHAUS; Fritz WAGNER; Dina FATTAKHOVA and Karlheinz SÜNKEL

Edition

Dalton Transactions, Royal Society of Chemistry, 2021, 1477-9226

Other information

Language

English

Type of outcome

Article in a journal

Field of Study

10404 Polymer science

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

is not subject to a state or trade secret

References:

URL

Impact factor

Impact factor: 4.569

RIV identification code

RIV/00216224:14310/21:00123145

Organization unit

Faculty of Science

DOI

https://doi.org/10.1039/d1dt02866a

UT WoS

000720965400001

EID Scopus

2-s2.0-85120955270

Keywords in English

CHARGE-TRANSFER COMPLEXES; ELECTRON-TRANSFER; CRYSTAL-STRUCTURES; METAL-COMPLEXES; OPEN FRAMEWORK; X-RAY; ANION; TRICYANOMETHANIDE; RADICALS; TCNQ

Abstract

In the original language

Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(ii) and iron(iii), silver(i) and potassium(i) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mossbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(i) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer.

Cite

NIMAX, Patrick René; Nils ROTTHOWE; Florian ZOLLER; Tobias BLOCKHAUS; Fritz WAGNER; Dina FATTAKHOVA and Karlheinz SÜNKEL. Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide. Dalton Transactions. Royal Society of Chemistry, 2021, vol. 50, No 47, p. 17643-17652. ISSN 1477-9226. Available from: https://doi.org/10.1039/d1dt02866a.

@article{1807861,
   author = {Nimax, Patrick René and Rotthowe, Nils and Zoller, Florian and Blockhaus, Tobias and Wagner, Fritz and Fattakhova, Dina and Sünkel, Karlheinz},
   article_number = {47},
   doi = {https://doi.org/10.1039/d1dt02866a},
   keywords = {CHARGE-TRANSFER COMPLEXES; ELECTRON-TRANSFER; CRYSTAL-STRUCTURES; METAL-COMPLEXES; OPEN FRAMEWORK; X-RAY; ANION; TRICYANOMETHANIDE; RADICALS; TCNQ},
   language = {eng},
   issn = {1477-9226},
   journal = {Dalton Transactions},
   title = {Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide},
   url = {https://pubs.rsc.org/en/content/articlelanding/2021/dt/d1dt02866a},
   volume = {50},
   year = {2021}
}

TY  - JOUR
ID  - 1807861
AU  - Nimax, Patrick René - Rotthowe, Nils - Zoller, Florian - Blockhaus, Tobias - Wagner, Fritz - Fattakhova, Dina - Sünkel, Karlheinz
PY  - 2021
TI  - Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide
JF  - Dalton Transactions
VL  - 50
IS  - 47
SP  - 17643-17652
EP  - 17643-17652
PB  - Royal Society of Chemistry
SN  - 14779226
KW  - CHARGE-TRANSFER COMPLEXES
KW  - ELECTRON-TRANSFER
KW  - CRYSTAL-STRUCTURES
KW  - METAL-COMPLEXES
KW  - OPEN FRAMEWORK
KW  - X-RAY
KW  - ANION
KW  - TRICYANOMETHANIDE
KW  - RADICALS
KW  - TCNQ
UR  - https://pubs.rsc.org/en/content/articlelanding/2021/dt/d1dt02866a
N2  - Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(ii) and iron(iii), silver(i) and potassium(i) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mossbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(i) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer.
ER  -

NIMAX, Patrick René; Nils ROTTHOWE; Florian ZOLLER; Tobias BLOCKHAUS; Fritz WAGNER; Dina FATTAKHOVA and Karlheinz SÜNKEL. Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide. \textit{Dalton Transactions}. Royal Society of Chemistry, 2021, vol.~50, No~47, p.~17643-17652. ISSN~1477-9226. Available from: https://doi.org/10.1039/d1dt02866a.

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