| NIMAX, Patrick René, Nils ROTTHOWE, Florian ZOLLER, Tobias BLOCKHAUS, Fritz WAGNER, Dina FATTAKHOVA and Karlheinz SÜNKEL. Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide. Dalton Transactions. Royal Society of Chemistry, 2021, vol. 50, No 47, p. 17643-17652. ISSN 1477-9226. Available from: https://dx.doi.org/10.1039/d1dt02866a. |
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@article{1807861,
author = {Nimax, Patrick René and Rotthowe, Nils and Zoller, Florian and Blockhaus, Tobias and Wagner, Fritz and Fattakhova, Dina and Sünkel, Karlheinz},
article_number = {47},
doi = {http://dx.doi.org/10.1039/d1dt02866a},
keywords = {CHARGE-TRANSFER COMPLEXES; ELECTRON-TRANSFER; CRYSTAL-STRUCTURES; METAL-COMPLEXES; OPEN FRAMEWORK; X-RAY; ANION; TRICYANOMETHANIDE; RADICALS; TCNQ},
language = {eng},
issn = {1477-9226},
journal = {Dalton Transactions},
title = {Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide},
url = {https://pubs.rsc.org/en/content/articlelanding/2021/dt/d1dt02866a},
volume = {50},
year = {2021}
}
TY - JOUR
ID - 1807861
AU - Nimax, Patrick René - Rotthowe, Nils - Zoller, Florian - Blockhaus, Tobias - Wagner, Fritz - Fattakhova, Dina - Sünkel, Karlheinz
PY - 2021
TI - Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide
JF - Dalton Transactions
VL - 50
IS - 47
SP - 17643-17652
EP - 17643-17652
PB - Royal Society of Chemistry
SN - 14779226
KW - CHARGE-TRANSFER COMPLEXES
KW - ELECTRON-TRANSFER
KW - CRYSTAL-STRUCTURES
KW - METAL-COMPLEXES
KW - OPEN FRAMEWORK
KW - X-RAY
KW - ANION
KW - TRICYANOMETHANIDE
KW - RADICALS
KW - TCNQ
UR - https://pubs.rsc.org/en/content/articlelanding/2021/dt/d1dt02866a
N2 - Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(ii) and iron(iii), silver(i) and potassium(i) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mossbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(i) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer.
ER -
NIMAX, Patrick René, Nils ROTTHOWE, Florian ZOLLER, Tobias BLOCKHAUS, Fritz WAGNER, Dina FATTAKHOVA and Karlheinz SÜNKEL. Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide. \textit{Dalton Transactions}. Royal Society of Chemistry, 2021, vol.~50, No~47, p.~17643-17652. ISSN~1477-9226. Available from: https://dx.doi.org/10.1039/d1dt02866a.
|
