Celleriite, ☐(⁠Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), a new
mineral species of the tourmaline supergroup

J 2022

Celleriite, ☐(⁠Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), a new mineral species of the tourmaline supergroup

BOSI, Ferdinando, Federico PEZZOTTA, Alessandra ALTIERI, Giovanni B. ANDREOZZI, Paolo BALLIRANO et. al.

Basic information

Original name

Celleriite, ☐(⁠Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), a new mineral species of the tourmaline supergroup

Authors

BOSI, Ferdinando (380 Italy), Federico PEZZOTTA (380 Italy), Alessandra ALTIERI (380 Italy), Giovanni B. ANDREOZZI (380 Italy), Paolo BALLIRANO (380 Italy), Gioacchino TEMPESTA (380 Italy), Jan CEMPÍREK (203 Czech Republic, belonging to the institution), Radek ŠKODA (203 Czech Republic, belonging to the institution), Jan FILIP (203 Czech Republic), Renata ČOPJAKOVÁ (203 Czech Republic, belonging to the institution), Milan NOVÁK (203 Czech Republic, belonging to the institution), Anthony R. KAMPF (840 United States of America), Emily D. SCRIBNER (124 Canada), Lee A. GROAT (124 Canada) and R. James EVANS (124 Canada)

Edition

American Mineralogist, Mineralogical Society of America, 2022, 0003-004X

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10504 Mineralogy

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 3.100

RIV identification code

RIV/00216224:14310/22:00119496

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.2138/am-2021-7818

UT WoS

000736146300003

Keywords in English

tourmaline; crystal-structure refinement; electron microprobe; Mössbauer spectroscopy; laser-induced breakdown spectroscopy; laser-ablation inductively coupled plasma massspectroscopy; Raman spectroscopy; Lithium; Beryllium; Boron

Abstract

V originále

Celleriite, ☐(⁠Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH), is a new mineral of the tourmaline supergroup. It was discovered in the Rosina pegmatite, San Piero in Campo, Elba Island, Italy (holotype specimen), and in the Pikárec pegmatite, western Moravia, Czech Republic (co-type specimen). Celleriite in hand specimen is violet to gray-blue (holotype) and dark brownish-green (co-type) with a vitreous luster, conchoidal fracture, and white streak. Celleriite has a Mohs hardness of ~7 and a calculated density of 3.13 and 3.14 g/cm3 for holotype and its co-type, respectively. In plane-polarized light in thin section, celleriite is pleochroic (O = pale violet and E = light gray-blue in holotype; O = pale green and E = colorless in co-type) and uniaxial negative. Celleriite has trigonal symmetry: space group R3m, Z = 3, a = 15.9518(4) and 15.9332(3) Å, c = 7.1579(2) and 7.13086(15) Å, V = 1577.38(9) and 1567.76(6) Å3 for holotype and co-type, respectively (data from single-crystal X-ray diffraction). The crystal structure of the holotype specimen was refined to R1 = 2.89% using 1696 unique reflections collected with MoKα X-ray intensity data. Structural, chemical, and spectroscopic analyses resulted in the formulas: x(□0.58Na0.42)Σ1.00Y(Mn2+1.39Fe2+0.16Mg0.01Al1.14Fe3+0.01Li0.28Ti0.01)Σ3.00ZAl6[T(Si5.99Al0.01)Σ6.00O18] (BO3)3(OH)3w[(OH)0.65F0.03O0.32]Σ1.00(for holotype) and x(□0.51Na0.49)Σ1.00Y(Mn2+0.90Fe2+0.50Al1.36Fe3+0.04Li0.17Zn0.04)Σ3.00ZAl6[T(Si5.75B0.25)Σ6.00O18] (BO3)3(OH)3w[(OH)0.35F0.17O0.48]Σ1.00(for co-type) Celleriite is a hydroxy species belonging to the X-site vacant group of the tourmaline supergroup. The new mineral was approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association, proposal no. 2019-089. In the Rosina pegmatite, celleriite formed an overgrowth at the analogous pole of elbaite–fluorelbaite–rossmanite crystals during the latest stage of evolution of pegmatite cavities after an event of a pocket rupture. In the Pikárec pegmatite, celleriite occurs as an intermediate growth sector of elbaite, princivalleite, and fluor-elbaite.

Links

GA17-17276S, research and development project

Name: Turmalín - indikátor geologických procesů

Investor: Czech Science Foundation

LM2018127, research and development project

Name: Česká infrastruktura pro integrativní strukturní biologii (Acronym: CIISB)

Investor: Ministry of Education, Youth and Sports of the CR

Citovat

BOSI, Ferdinando, Federico PEZZOTTA, Alessandra ALTIERI, Giovanni B. ANDREOZZI, Paolo BALLIRANO, Gioacchino TEMPESTA, Jan CEMPÍREK, Radek ŠKODA, Jan FILIP, Renata ČOPJAKOVÁ, Milan NOVÁK, Anthony R. KAMPF, Emily D. SCRIBNER, Lee A. GROAT and R. James EVANS. Celleriite, ☐(⁠Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), a new mineral species of the tourmaline supergroup. American Mineralogist. Mineralogical Society of America, 2022, vol. 107, No 1, p. 31-42. ISSN 0003-004X. Available from: https://dx.doi.org/10.2138/am-2021-7818.

@article{1816417,
   author = {Bosi, Ferdinando and Pezzotta, Federico and Altieri, Alessandra and Andreozzi, Giovanni B. and Ballirano, Paolo and Tempesta, Gioacchino and Cempírek, Jan and Škoda, Radek and Filip, Jan and Čopjaková, Renata and Novák, Milan and Kampf, Anthony R. and Scribner, Emily D. and Groat, Lee A. and Evans, R. James},
   article_number = {1},
   doi = {http://dx.doi.org/10.2138/am-2021-7818},
   keywords = {tourmaline; crystal-structure refinement; electron microprobe; Mössbauer spectroscopy; laser-induced breakdown spectroscopy; laser-ablation inductively coupled plasma massspectroscopy; Raman spectroscopy; Lithium; Beryllium; Boron},
   language = {eng},
   issn = {0003-004X},
   journal = {American Mineralogist},
   title = {Celleriite, ☐(⁠Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), a new mineral species of the tourmaline supergroup},
   url = {https://doi.org/10.2138/am-2021-7818},
   volume = {107},
   year = {2022}
}

TY  - JOUR
ID  - 1816417
AU  - Bosi, Ferdinando - Pezzotta, Federico - Altieri, Alessandra - Andreozzi, Giovanni B. - Ballirano, Paolo - Tempesta, Gioacchino - Cempírek, Jan - Škoda, Radek - Filip, Jan - Čopjaková, Renata - Novák, Milan - Kampf, Anthony R. - Scribner, Emily D. - Groat, Lee A. - Evans, R. James
PY  - 2022
TI  - Celleriite, ☐(⁠Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), a new mineral species of the tourmaline supergroup
JF  - American Mineralogist
VL  - 107
IS  - 1
SP  - 31-42
EP  - 31-42
PB  - Mineralogical Society of America
SN  - 0003004X
KW  - tourmaline
KW  - crystal-structure refinement
KW  - electron microprobe
KW  - Mössbauer spectroscopy
KW  - laser-induced breakdown spectroscopy
KW  - laser-ablation inductively coupled plasma massspectroscopy
KW  - Raman spectroscopy
KW  - Lithium
KW  - Beryllium
KW  - Boron
UR  - https://doi.org/10.2138/am-2021-7818
N2  - Celleriite, ☐(⁠Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH), is a new mineral of the tourmaline supergroup. It was discovered in the Rosina pegmatite, San Piero in Campo, Elba Island, Italy (holotype specimen), and in the Pikárec pegmatite, western Moravia, Czech Republic (co-type specimen). Celleriite in hand specimen is violet to gray-blue (holotype) and dark brownish-green (co-type) with a vitreous luster, conchoidal fracture, and white streak. Celleriite has a Mohs hardness of ~7 and a calculated density of 3.13 and 3.14 g/cm3 for holotype and its co-type, respectively. In plane-polarized light in thin section, celleriite is pleochroic (O = pale violet and E = light gray-blue in holotype; O = pale green and E = colorless in co-type) and uniaxial negative. Celleriite has trigonal symmetry: space group R3m, Z = 3, a = 15.9518(4) and 15.9332(3) Å, c = 7.1579(2) and 7.13086(15) Å, V = 1577.38(9) and 1567.76(6) Å3 for holotype and co-type, respectively (data from single-crystal X-ray diffraction). The crystal structure of the holotype specimen was refined to R1 = 2.89% using 1696 unique reflections collected with MoKα X-ray intensity data. Structural, chemical, and spectroscopic analyses resulted in the formulas: x(□0.58Na0.42)Σ1.00Y(Mn2+1.39Fe2+0.16Mg0.01Al1.14Fe3+0.01Li0.28Ti0.01)Σ3.00ZAl6[T(Si5.99Al0.01)Σ6.00O18] (BO3)3(OH)3w[(OH)0.65F0.03O0.32]Σ1.00(for holotype) and x(□0.51Na0.49)Σ1.00Y(Mn2+0.90Fe2+0.50Al1.36Fe3+0.04Li0.17Zn0.04)Σ3.00ZAl6[T(Si5.75B0.25)Σ6.00O18] (BO3)3(OH)3w[(OH)0.35F0.17O0.48]Σ1.00(for co-type) Celleriite is a hydroxy species belonging to the X-site vacant group of the tourmaline supergroup. The new mineral was approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association, proposal no. 2019-089. In the Rosina pegmatite, celleriite formed an overgrowth at the analogous pole of elbaite–fluorelbaite–rossmanite crystals during the latest stage of evolution of pegmatite cavities after an event of a pocket rupture. In the Pikárec pegmatite, celleriite occurs as an intermediate growth sector of elbaite, princivalleite, and fluor-elbaite.
ER  -

BOSI, Ferdinando, Federico PEZZOTTA, Alessandra ALTIERI, Giovanni B. ANDREOZZI, Paolo BALLIRANO, Gioacchino TEMPESTA, Jan CEMPÍREK, Radek ŠKODA, Jan FILIP, Renata ČOPJAKOVÁ, Milan NOVÁK, Anthony R. KAMPF, Emily D. SCRIBNER, Lee A. GROAT and R. James EVANS. Celleriite, ☐(⁠Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), a new mineral species of the tourmaline supergroup. \textit{American Mineralogist}. Mineralogical Society of America, 2022, vol.~107, No~1, p.~31-42. ISSN~0003-004X. Available from: https://dx.doi.org/10.2138/am-2021-7818.

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