Fluorinated Bambus[6]urils for Anion Binding in Water

LAPEŠOVÁ, Jana, Jan SOKOLOV and Vladimír ŠINDELÁŘ. Fluorinated Bambus[6]urils for Anion Binding in Water. In 55th Conference: Advances in Organic, Bioorganic and Pharmaceutical Chemistry – Liblice 2021, Špindlerův Mlýn, Czech Republic, 3 - 6 November 2021. 2021.

Basic information

• Original name: Fluorinated Bambus[6]urils for Anion Binding in Water
• Authors: LAPEŠOVÁ, Jana, Jan SOKOLOV and Vladimír ŠINDELÁŘ.
• Edition: 55th Conference: Advances in Organic, Bioorganic and Pharmaceutical Chemistry – Liblice 2021, Špindlerův Mlýn, Czech Republic, 3 - 6 November 2021, 2021.

Other information

• Type of outcome: Conference abstract
• Confidentiality degree: is not subject to a state or trade secret

Abstract

Anion binding in water can be beneficial for many reasons, e.g., simple anion analysis, removal of toxic anions, or anion transport. However, development of synthetic anion receptors is a complex problem due to very competitive character of aqueous media. Bambus[6]urils have been recognized as potent anion receptors in various media. Water-solubility was successfully achieved by introducing carboxylate groups onto the macrocycle. Affinity of bambus[6]urils toward anions was enhanced introducing electron withdrawing groups to their structure. The aim of this project is to synthesize a water-soluble bambus[6]urils with high affinity toward anions. We suggest several strategies for preparation of water soluble fluorinated bambus[6]uril including than one in which the macrocycle is prepared from glycoluril monomers bearing both polar and fluorinated groups. Synthesis of these glycoluril derivatives and resulting bambus[6]urils will be presented.

Links

• MUNI/C/1841/2020, interní kód MU: Name: Fluorované bambus[6]urily pro vázání aniontů ve vodě

Investor: Masaryk University, Excellent diploma thesis