| SAVENKO, M., Timothée Emmanuel J. RIVEL, S. YESYLEVSKYY and C. RAMSEYER. Influence of Substrate Hydrophilicity on Structural Properties of Supported Lipid Systems on Graphene, Graphene Oxides, and Silica. Journal of Physical Chemistry B. Washington, D.C.: American Chemical Society, 2021, vol. 125, No 29, p. 8060-8074. ISSN 1520-6106. Available from: https://dx.doi.org/10.1021/acs.jpcb.1c04615. |
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@article{1838621,
author = {Savenko, M. and Rivel, Timothée Emmanuel J. and Yesylevskyy, S. and Ramseyer, C.},
article_location = {Washington, D.C.},
article_number = {29},
doi = {http://dx.doi.org/10.1021/acs.jpcb.1c04615},
keywords = {PHOSPHOLIPID-BILAYER FORMATIONMOLECULAR-DYNAMICSNEUTRON REFLECTIVITYMEMBRANE ORGANIZATIONVESICLE ADSORPTIONFORCE-FIELDSURFACEWATERSINGLEMODEL},
language = {eng},
issn = {1520-6106},
journal = {Journal of Physical Chemistry B},
title = {Influence of Substrate Hydrophilicity on Structural Properties of Supported Lipid Systems on Graphene, Graphene Oxides, and Silica},
url = {https://pubs.acs.org/doi/10.1021/acs.jpcb.1c04615},
volume = {125},
year = {2021}
}
TY - JOUR
ID - 1838621
AU - Savenko, M. - Rivel, Timothée Emmanuel J. - Yesylevskyy, S. - Ramseyer, C.
PY - 2021
TI - Influence of Substrate Hydrophilicity on Structural Properties of Supported Lipid Systems on Graphene, Graphene Oxides, and Silica
JF - Journal of Physical Chemistry B
VL - 125
IS - 29
SP - 8060-8074
EP - 8060-8074
PB - American Chemical Society
SN - 15206106
KW - PHOSPHOLIPID-BILAYER FORMATIONMOLECULAR-DYNAMICSNEUTRON REFLECTIVITYMEMBRANE ORGANIZATIONVESICLE ADSORPTIONFORCE-FIELDSURFACEWATERSINGLEMODEL
UR - https://pubs.acs.org/doi/10.1021/acs.jpcb.1c04615
N2 - Pristine graphene, a range of graphene oxides, and silica substrates were used to investigate the effect of surface hydrophilicity on supported lipid bilayers by means of all-atom molecular dynamics simulations. Supported 1,2-dioleoyl-sn-glycero-3-phosphocholine lipid bilayers were found in close-contact conformations with hydrophilic substrates with as low as 5% oxidation level, while self-assembled monolayers occur on pure hydrophobic graphene only. Lipids and water at the surface undergo large redistribution to maintain the stability of the supported bilayers. Deposition of bicelles on increasingly hydrophilic substrates shows the continuous process of reshaping of the supported system and makes intermediate stages between self-assembled monolayers and supported bilayers. The bilayer thickness changes with hydrophilicity in a complex manner, while the number of water molecules per lipid in the hydration layer increases together with hydrophilicity.
ER -
SAVENKO, M., Timothée Emmanuel J. RIVEL, S. YESYLEVSKYY and C. RAMSEYER. Influence of Substrate Hydrophilicity on Structural Properties of Supported Lipid Systems on Graphene, Graphene Oxides, and Silica. \textit{Journal of Physical Chemistry B}. Washington, D.C.: American Chemical Society, 2021, vol.~125, No~29, p.~8060-8074. ISSN~1520-6106. Available from: https://dx.doi.org/10.1021/acs.jpcb.1c04615.
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