| SKODA, David, Barbora HANULIKOVA, Aleš STÝSKALÍK, Vít VYKOUKAL, Petr MACHÁČ, Pavel URBANEK, Eva DOMINCOVA BERGEROVA, Lucie ŠIMONÍKOVÁ and Ivo KURITKA. Non-aqueous synthesis of homogeneous molybdenum silicate microspheres and their application as heterogeneous catalysts in olefin epoxidation and selective aniline oxidation. Journal of Industrial and Engineering Chemistry. Elsevier, 2022, vol. 107, March, p. 320-332. ISSN 1226-086X. Available from: https://dx.doi.org/10.1016/j.jiec.2021.12.001. |
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@article{1842558,
author = {Skoda, David and Hanulikova, Barbora and Stýskalík, Aleš and Vykoukal, Vít and Macháč, Petr and Urbanek, Pavel and Domincova Bergerova, Eva and Šimoníková, Lucie and Kuritka, Ivo},
article_number = {March},
doi = {http://dx.doi.org/10.1016/j.jiec.2021.12.001},
keywords = {Molybdenum silicate; Non-aqueous; Microspheres; Catalyst; Epoxidation; Aniline oxidation},
language = {eng},
issn = {1226-086X},
journal = {Journal of Industrial and Engineering Chemistry},
title = {Non-aqueous synthesis of homogeneous molybdenum silicate microspheres and their application as heterogeneous catalysts in olefin epoxidation and selective aniline oxidation},
url = {https://www.sciencedirect.com/science/article/pii/S1226086X21006572},
volume = {107},
year = {2022}
}
TY - JOUR
ID - 1842558
AU - Skoda, David - Hanulikova, Barbora - Stýskalík, Aleš - Vykoukal, Vít - Macháč, Petr - Urbanek, Pavel - Domincova Bergerova, Eva - Šimoníková, Lucie - Kuritka, Ivo
PY - 2022
TI - Non-aqueous synthesis of homogeneous molybdenum silicate microspheres and their application as heterogeneous catalysts in olefin epoxidation and selective aniline oxidation
JF - Journal of Industrial and Engineering Chemistry
VL - 107
IS - March
SP - 320-332
EP - 320-332
PB - Elsevier
SN - 1226086X
KW - Molybdenum silicate
KW - Non-aqueous
KW - Microspheres
KW - Catalyst
KW - Epoxidation
KW - Aniline oxidation
UR - https://www.sciencedirect.com/science/article/pii/S1226086X21006572
N2 - In this work, a novel synthesis of homogeneous molybdenum silicate spheres under non-aqueous conditions is presented. A preparation method is based on the condensation of molybdenum metal–organic framework-based precursor solution prepared via a microwave-assisted approach from bis(acetylacetonato)dioxomolybdenum and biphenyl-4,4′-dicarboxylic acid with 3-aminopropyltriethoxysilane under non-aqueous conditions. The as-prepared product was calcined at 500 °C to obtain amorphous and porous molybdenum silicate microspheres with homogeneously distributed molybdenum species within silicate matrix. The microspheres exhibit an average size of about 480 nm. This material was further studied as a heterogeneous catalyst for the epoxidation of olefins via the model catalytic epoxidation of cyclohexene with cumylhydroperoxide. High catalytic activity at the moderate temperature (65 °C) with the conversion of 86% after 2 h and the high selectivity to cyclohexene oxide has been achieved. In addition, molybdenum silicate microspheres exhibit catalytic activity and high selectivity in the oxidation of aniline to nitrosobenzene.
ER -
SKODA, David, Barbora HANULIKOVA, Aleš STÝSKALÍK, Vít VYKOUKAL, Petr MACHÁČ, Pavel URBANEK, Eva DOMINCOVA BERGEROVA, Lucie ŠIMONÍKOVÁ and Ivo KURITKA. Non-aqueous synthesis of homogeneous molybdenum silicate microspheres and their application as heterogeneous catalysts in olefin epoxidation and selective aniline oxidation. \textit{Journal of Industrial and Engineering Chemistry}. Elsevier, 2022, vol.~107, March, p.~320-332. ISSN~1226-086X. Available from: https://dx.doi.org/10.1016/j.jiec.2021.12.001.
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