Non-aqueous synthesis of homogeneous molybdenum silicate
microspheres and their application as heterogeneous catalysts
in olefin epoxidation and selective aniline oxidation

J 2022

Non-aqueous synthesis of homogeneous molybdenum silicate microspheres and their application as heterogeneous catalysts in olefin epoxidation and selective aniline oxidation

SKODA, David, Barbora HANULIKOVA, Aleš STÝSKALÍK, Vít VYKOUKAL, Petr MACHÁČ et. al.

Basic information

Original name

Non-aqueous synthesis of homogeneous molybdenum silicate microspheres and their application as heterogeneous catalysts in olefin epoxidation and selective aniline oxidation

Authors

SKODA, David (guarantor), Barbora HANULIKOVA, Aleš STÝSKALÍK (203 Czech Republic, belonging to the institution), Vít VYKOUKAL (203 Czech Republic, belonging to the institution), Petr MACHÁČ (203 Czech Republic, belonging to the institution), Pavel URBANEK, Eva DOMINCOVA BERGEROVA, Lucie ŠIMONÍKOVÁ (203 Czech Republic, belonging to the institution) and Ivo KURITKA

Edition

Journal of Industrial and Engineering Chemistry, Elsevier, 2022, 1226-086X

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10403 Physical chemistry

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 6.100

RIV identification code

RIV/00216224:14310/22:00125560

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1016/j.jiec.2021.12.001

UT WoS

000787815800004

Keywords in English

Molybdenum silicate; Non-aqueous; Microspheres; Catalyst; Epoxidation; Aniline oxidation

Abstract

V originále

In this work, a novel synthesis of homogeneous molybdenum silicate spheres under non-aqueous conditions is presented. A preparation method is based on the condensation of molybdenum metal–organic framework-based precursor solution prepared via a microwave-assisted approach from bis(acetylacetonato)dioxomolybdenum and biphenyl-4,4′-dicarboxylic acid with 3-aminopropyltriethoxysilane under non-aqueous conditions. The as-prepared product was calcined at 500 °C to obtain amorphous and porous molybdenum silicate microspheres with homogeneously distributed molybdenum species within silicate matrix. The microspheres exhibit an average size of about 480 nm. This material was further studied as a heterogeneous catalyst for the epoxidation of olefins via the model catalytic epoxidation of cyclohexene with cumylhydroperoxide. High catalytic activity at the moderate temperature (65 °C) with the conversion of 86% after 2 h and the high selectivity to cyclohexene oxide has been achieved. In addition, molybdenum silicate microspheres exhibit catalytic activity and high selectivity in the oxidation of aniline to nitrosobenzene.

Links

GJ20-03636Y, research and development project

Name: Nové katalyzátory pro přípravu 1,3-butadienu z ethanolu

Investor: Czech Science Foundation

90110, large research infrastructures

Name: CzechNanoLab

90127, large research infrastructures

Name: CIISB II

Citovat

SKODA, David, Barbora HANULIKOVA, Aleš STÝSKALÍK, Vít VYKOUKAL, Petr MACHÁČ, Pavel URBANEK, Eva DOMINCOVA BERGEROVA, Lucie ŠIMONÍKOVÁ and Ivo KURITKA. Non-aqueous synthesis of homogeneous molybdenum silicate microspheres and their application as heterogeneous catalysts in olefin epoxidation and selective aniline oxidation. Journal of Industrial and Engineering Chemistry. Elsevier, 2022, vol. 107, March, p. 320-332. ISSN 1226-086X. Available from: https://dx.doi.org/10.1016/j.jiec.2021.12.001.

@article{1842558,
   author = {Skoda, David and Hanulikova, Barbora and Stýskalík, Aleš and Vykoukal, Vít and Macháč, Petr and Urbanek, Pavel and Domincova Bergerova, Eva and Šimoníková, Lucie and Kuritka, Ivo},
   article_number = {March},
   doi = {http://dx.doi.org/10.1016/j.jiec.2021.12.001},
   keywords = {Molybdenum silicate; Non-aqueous; Microspheres; Catalyst; Epoxidation; Aniline oxidation},
   language = {eng},
   issn = {1226-086X},
   journal = {Journal of Industrial and Engineering Chemistry},
   title = {Non-aqueous synthesis of homogeneous molybdenum silicate microspheres and their application as heterogeneous catalysts in olefin epoxidation and selective aniline oxidation},
   url = {https://www.sciencedirect.com/science/article/pii/S1226086X21006572},
   volume = {107},
   year = {2022}
}

TY  - JOUR
ID  - 1842558
AU  - Skoda, David - Hanulikova, Barbora - Stýskalík, Aleš - Vykoukal, Vít - Macháč, Petr - Urbanek, Pavel - Domincova Bergerova, Eva - Šimoníková, Lucie - Kuritka, Ivo
PY  - 2022
TI  - Non-aqueous synthesis of homogeneous molybdenum silicate microspheres and their application as heterogeneous catalysts in olefin epoxidation and selective aniline oxidation
JF  - Journal of Industrial and Engineering Chemistry
VL  - 107
IS  - March
SP  - 320-332
EP  - 320-332
PB  - Elsevier
SN  - 1226086X
KW  - Molybdenum silicate
KW  - Non-aqueous
KW  - Microspheres
KW  - Catalyst
KW  - Epoxidation
KW  - Aniline oxidation
UR  - https://www.sciencedirect.com/science/article/pii/S1226086X21006572
N2  - In this work, a novel synthesis of homogeneous molybdenum silicate spheres under non-aqueous conditions is presented. A preparation method is based on the condensation of molybdenum metal–organic framework-based precursor solution prepared via a microwave-assisted approach from bis(acetylacetonato)dioxomolybdenum and biphenyl-4,4′-dicarboxylic acid with 3-aminopropyltriethoxysilane under non-aqueous conditions. The as-prepared product was calcined at 500 °C to obtain amorphous and porous molybdenum silicate microspheres with homogeneously distributed molybdenum species within silicate matrix. The microspheres exhibit an average size of about 480 nm. This material was further studied as a heterogeneous catalyst for the epoxidation of olefins via the model catalytic epoxidation of cyclohexene with cumylhydroperoxide. High catalytic activity at the moderate temperature (65 °C) with the conversion of 86% after 2 h and the high selectivity to cyclohexene oxide has been achieved. In addition, molybdenum silicate microspheres exhibit catalytic activity and high selectivity in the oxidation of aniline to nitrosobenzene.
ER  -

SKODA, David, Barbora HANULIKOVA, Aleš STÝSKALÍK, Vít VYKOUKAL, Petr MACHÁČ, Pavel URBANEK, Eva DOMINCOVA BERGEROVA, Lucie ŠIMONÍKOVÁ and Ivo KURITKA. Non-aqueous synthesis of homogeneous molybdenum silicate microspheres and their application as heterogeneous catalysts in olefin epoxidation and selective aniline oxidation. \textit{Journal of Industrial and Engineering Chemistry}. Elsevier, 2022, vol.~107, March, p.~320-332. ISSN~1226-086X. Available from: https://dx.doi.org/10.1016/j.jiec.2021.12.001.

Detailed Information on Publication Record