Multiresponsive 2D Ti3C2Tx MXene via Implanting Molecular
Properties

J 2021

Multiresponsive 2D Ti3C2Tx MXene via Implanting Molecular Properties

MAYORGA-BURREZO, P., J. MUNOZ, D. ZAORALOVA, M. OTYEPKA, M. PUMERA et. al.

Basic information

Original name

Multiresponsive 2D Ti3C2Tx MXene via Implanting Molecular Properties

Authors

MAYORGA-BURREZO, P., J. MUNOZ, D. ZAORALOVA, M. OTYEPKA and M. PUMERA

Edition

ACS Nano, WASHINGTON, American Chemical Society, 2021, 1936-0851

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10400 1.4 Chemical sciences

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 18.027

RIV identification code

RIV/00216224:14740/21:00124447

Organization unit

Central European Institute of Technology

DOI

http://dx.doi.org/10.1021/acsnano.1c01742

UT WoS

000665748900074

Keywords in English

2D materials; surface engineering; chiral MXene; fluorescence; molecular switches; supramolecular recognition; electronic devices

Abstract

V originále

The design and fabrication of active nanomaterials exhibiting multifunctional properties is a must in the socalled global "Fourth Industrial Revolution". In this sense, molecular engineering is a powerful tool to implant original capabilities on a macroscopic scale. Herein, different bio-inspired 2D-MXenes have been developed via a versatile and straightforward synthetic approach. As a proof of concept, Ti3C2Tx MXene has been exploited as a highly sensitive transducing platform for the covalent assembly of active biomolecular architectures (i.e., amino acids). All pivotal properties originated from the anchored targets were proved to be successfully transferred to the resulting bioinspired 2D-MXenes. Appealing applications have been devised for these 2D-MXene prototypes showing (i) chiroptical activity, (ii) fluorescence capabilities, (iii) supramolecular pi-pi interactions, and (iv) stimuli-responsive molecular switchability. Overall, this work demonstrates the fabrication of programmable 2D-MXenes, taking advantage of the inherent characteristics of the implanted (bio)molecular components. Thus, the current bottleneck in the field of 2D-MXenes can be overcome after the significant findings reported here.

Links

90127, large research infrastructures

Name: CIISB II

Citovat

MAYORGA-BURREZO, P., J. MUNOZ, D. ZAORALOVA, M. OTYEPKA and M. PUMERA. Multiresponsive 2D Ti3C2Tx MXene via Implanting Molecular Properties. ACS Nano. WASHINGTON: American Chemical Society, 2021, vol. 15, No 6, p. 10067-10075. ISSN 1936-0851. Available from: https://dx.doi.org/10.1021/acsnano.1c01742.

@article{1842618,
   author = {MayorgaandBurrezo, P. and Munoz, J. and Zaoralova, D. and Otyepka, M. and Pumera, M.},
   article_location = {WASHINGTON},
   article_number = {6},
   doi = {http://dx.doi.org/10.1021/acsnano.1c01742},
   keywords = {2D materials; surface engineering; chiral MXene; fluorescence; molecular switches; supramolecular recognition; electronic devices},
   language = {eng},
   issn = {1936-0851},
   journal = {ACS Nano},
   title = {Multiresponsive 2D Ti3C2Tx MXene via Implanting Molecular Properties},
   url = {https://pubs.acs.org/doi/10.1021/acsnano.1c01742},
   volume = {15},
   year = {2021}
}

TY  - JOUR
ID  - 1842618
AU  - Mayorga-Burrezo, P. - Munoz, J. - Zaoralova, D. - Otyepka, M. - Pumera, M.
PY  - 2021
TI  - Multiresponsive 2D Ti3C2Tx MXene via Implanting Molecular Properties
JF  - ACS Nano
VL  - 15
IS  - 6
SP  - 10067-10075
EP  - 10067-10075
PB  - American Chemical Society
SN  - 19360851
KW  - 2D materials
KW  - surface engineering
KW  - chiral MXene
KW  - fluorescence
KW  - molecular switches
KW  - supramolecular recognition
KW  - electronic devices
UR  - https://pubs.acs.org/doi/10.1021/acsnano.1c01742
N2  - The design and fabrication of active nanomaterials exhibiting multifunctional properties is a must in the socalled global "Fourth Industrial Revolution". In this sense, molecular engineering is a powerful tool to implant original capabilities on a macroscopic scale. Herein, different bio-inspired 2D-MXenes have been developed via a versatile and straightforward synthetic approach. As a proof of concept, Ti3C2Tx MXene has been exploited as a highly sensitive transducing platform for the covalent assembly of active biomolecular architectures (i.e., amino acids). All pivotal properties originated from the anchored targets were proved to be successfully transferred to the resulting bioinspired 2D-MXenes. Appealing applications have been devised for these 2D-MXene prototypes showing (i) chiroptical activity, (ii) fluorescence capabilities, (iii) supramolecular pi-pi interactions, and (iv) stimuli-responsive molecular switchability. Overall, this work demonstrates the fabrication of programmable 2D-MXenes, taking advantage of the inherent characteristics of the implanted (bio)molecular components. Thus, the current bottleneck in the field of 2D-MXenes can be overcome after the significant findings reported here.
ER  -

MAYORGA-BURREZO, P., J. MUNOZ, D. ZAORALOVA, M. OTYEPKA and M. PUMERA. Multiresponsive 2D Ti3C2Tx MXene via Implanting Molecular Properties. \textit{ACS Nano}. WASHINGTON: American Chemical Society, 2021, vol.~15, No~6, p.~10067-10075. ISSN~1936-0851. Available from: https://dx.doi.org/10.1021/acsnano.1c01742.

Detailed Information on Publication Record