Crystallization of Uranyl Silicate Natroboltwoodite during an
Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal
Structure and Raman Spectroscopy

J 2022

Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy

PLÁŠIL, Jakub; Radek ŠKODA and Karolína FATKOVÁ

Basic information

Original name

Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy

Authors

PLÁŠIL, Jakub (guarantor); Radek ŠKODA (203 Czech Republic, belonging to the institution) and Karolína FATKOVÁ (203 Czech Republic, belonging to the institution)

Edition

Crystal Growth and Design, American Chemical Society, 2022, 1528-7483

Other information

Language

English

Type of outcome

Article in a journal

Field of Study

10504 Mineralogy

Country of publisher

United States of America

Confidentiality degree

is not subject to a state or trade secret

References:

URL

Impact factor

Impact factor: 3.800

RIV identification code

RIV/00216224:14310/22:00125713

Organization unit

Faculty of Science

DOI

https://doi.org/10.1021/acs.cgd.1c01152

UT WoS

000757590600001

EID Scopus

2-s2.0-85123848511

Keywords in English

Dissolution; Minerals; Cations; Crystals; Crystal structure

Abstract

In the original language

A synthetic analogue of the mineral natroboltwoodite was obtained unprecedently during a dissolution experiment with the mineral yttrialite-(Y), at a temperature of 200 °C, pressure ∼1.5 MPa, and strongly alkaline conditions. Natroboltwoodite formed along with analcime and aegirine. Single crystals of natroboltwoodite obtained allowed us to reveal its crystal structure for the first time. It differs from the other known uranyl silicate structures in the size of its respective unit-cell volume. The increased size of the structure corresponds to the positional and occupational disorder among one of the Si-tetrahedrally coordinated sites. On the basis of structural complexity parameters, a comparison involving both known synthetic and naturally occurring uranyl silicates is provided and discussed.

Links

EF16_026/0008459, research and development project

Name: Dlouhodobý výzkum geochemických bariér pro ukládání jaderného odpadu

Cite

PLÁŠIL, Jakub; Radek ŠKODA and Karolína FATKOVÁ. Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy. Crystal Growth and Design. American Chemical Society, 2022, vol. 22, No 2, p. 1202 - 1211. ISSN 1528-7483. Available from: https://doi.org/10.1021/acs.cgd.1c01152.

@article{1849318,
   author = {Plášil, Jakub and Škoda, Radek and Fatková, Karolína},
   article_number = {2},
   doi = {https://doi.org/10.1021/acs.cgd.1c01152},
   keywords = {Dissolution; Minerals; Cations; Crystals; Crystal structure},
   language = {eng},
   issn = {1528-7483},
   journal = {Crystal Growth and Design},
   title = {Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy},
   url = {https://pubs.acs.org/doi/abs/10.1021/acs.cgd.1c01152},
   volume = {22},
   year = {2022}
}

TY  - JOUR
ID  - 1849318
AU  - Plášil, Jakub - Škoda, Radek - Fatková, Karolína
PY  - 2022
TI  - Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy
JF  - Crystal Growth and Design
VL  - 22
IS  - 2
SP  - 1202 - 1211
EP  - 1202 - 1211
PB  - American Chemical Society
SN  - 15287483
KW  - Dissolution
KW  - Minerals
KW  - Cations
KW  - Crystals
KW  - Crystal structure
UR  - https://pubs.acs.org/doi/abs/10.1021/acs.cgd.1c01152
N2  - A synthetic analogue of the mineral natroboltwoodite was obtained unprecedently during a dissolution experiment with the mineral yttrialite-(Y), at a temperature of 200 °C, pressure ∼1.5 MPa, and strongly alkaline conditions. Natroboltwoodite formed along with analcime and aegirine. Single crystals of natroboltwoodite obtained allowed us to reveal its crystal structure for the first time. It differs from the other known uranyl silicate structures in the size of its respective unit-cell volume. The increased size of the structure corresponds to the positional and occupational disorder among one of the Si-tetrahedrally coordinated sites. On the basis of structural complexity parameters, a comparison involving both known synthetic and naturally occurring uranyl silicates is provided and discussed.
ER  -

PLÁŠIL, Jakub; Radek ŠKODA and Karolína FATKOVÁ. Crystallization of Uranyl Silicate Natroboltwoodite during an Experimental Dissolution of the Mineral Yttrialite-(Y): Crystal Structure and Raman Spectroscopy. \textit{Crystal Growth and Design}. American Chemical Society, 2022, vol.~22, No~2, p.~1202 - 1211. ISSN~1528-7483. Available from: https://doi.org/10.1021/acs.cgd.1c01152.

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