NOUASRIA, F. Z., D. SELLOUM, A. HENNI, S. TINGRY and Jan HRBÁČ. Improvement of the photocatalytic performance of ZnO thin films in the UV and sunlight range by Cu doping and additional coupling with Cu2O. Ceramics International. Elsevier Ltd, 2022, vol. 48, No 9, p. 13283-13294. ISSN 0272-8842. Available from: https://dx.doi.org/10.1016/j.ceramint.2022.01.207.
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Basic information
Original name Improvement of the photocatalytic performance of ZnO thin films in the UV and sunlight range by Cu doping and additional coupling with Cu2O
Authors NOUASRIA, F. Z., D. SELLOUM (guarantor), A. HENNI, S. TINGRY and Jan HRBÁČ (203 Czech Republic, belonging to the institution).
Edition Ceramics International, Elsevier Ltd, 2022, 0272-8842.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10403 Physical chemistry
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
WWW URL URL
Impact factor Impact factor: 5.200
RIV identification code RIV/00216224:14310/22:00125869
Organization unit Faculty of Science
Doi http://dx.doi.org/10.1016/j.ceramint.2022.01.207
UT WoS 000784446000002
Keywords in English Thin films; Heterojunction; Electrodeposition; Photocatalysis; Sunlight irradiation; Organic dyes
Tags rivok
Tags International impact, Reviewed
Changed by Changed by: Mgr. Marie Šípková, DiS., učo 437722. Changed: 10/1/2023 11:02.
Abstract
Thin films of ZnO, Cu-doped ZnO, Cu2O and binary Cu2O/Cu-doped ZnO p-n heterojunction thin film were prepared and tested for their heterogeneous photocatalytic activity in the removal of three selected organic dyes: methylene blue (MB), methylene orange (MO) and Congo red (CR). The photocatalytic experiments were carried out under UV light and natural sunlight. The synthesis of the thin film photocatalysts was carried out by an electrochemical deposition method and the resulting films were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), UV-Vis spectroscopy, electrochemical impedance spectroscopy and capacitance measurements (i.e., Mott-Schottky plots). Under UV illumination, the results showed that the photocatalytic degradation activity is of first-order kinetics and the lifetime of the photogenerated electron-hole pairs of ZnO is increased by the Cu doping. The combination of Cu-doped ZnO and Cu2O allows the construction of a p-n heterojunction that enhances the photocatalytic process, as demonstrated for the photocatalytic degradation of dyes under sunlight irradiation.
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