| ALBERTI, Milan, Josef BŘÍNEK, Jaromír MAREK and Jiří TOUŽÍN. The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2). (The Reaction of [P3N3Cl4(NH2)2] with [HN(POCl2)2]; the Crystal Structure of a Phosphazenium Salt [P3N3HCl4(NH2)2]+ [N(POCl2)2]-.). Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]. Heidelberg: Johan Ambrosius Barth Verlag, 1997, vol. 1997, No 623, p. 637-641. ISSN 0044-2313. |
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@article{197886,
author = {Alberti, Milan and Břínek, Josef and Marek, Jaromír and Toužín, Jiří},
article_location = {Heidelberg},
article_number = {623},
keywords = {preparation; crystal structure; molecular structure; vibrational spectra},
language = {eng},
issn = {0044-2313},
journal = {Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]},
title = {The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2).},
volume = {1997},
year = {1997}
}
TY - JOUR
ID - 197886
AU - Alberti, Milan - Břínek, Josef - Marek, Jaromír - Toužín, Jiří
PY - 1997
TI - The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2).
JF - Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]
VL - 1997
IS - 623
SP - 637
EP - 637
PB - Johan Ambrosius Barth Verlag
SN - 00442313
KW - preparation
KW - crystal structure
KW - molecular structure
KW - vibrational spectra
N2 - P3N3Cl5(NH2) in high purity and good yield can be obtained by the reaction of P3N3Cl4(NH2)2 with gaseous HCl in acetonitrile If diethylether or dichlormethane is used as a solvent, a salt-like compound [P3N3Cl4H(NH2)2+Cl- is formed as a microcrystalline product instead of P3N3Cl5(NH2). The crystal structure of P3N3Cl5(NH2)was determined by X-ray structure analysis. Vibrational spectra and thermic behavior of both P3N3Cl5(NH2)and [P3N3Cl4H(NH2)2+Cl- are also briefly discussed.
ER -
ALBERTI, Milan, Josef BŘÍNEK, Jaromír MAREK and Jiří TOUŽÍN. The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2). (The Reaction of [P3N3Cl4(NH2)2] with [HN(POCl2)2]; the Crystal Structure of a Phosphazenium Salt [P3N3HCl4(NH2)2]+ [N(POCl2)2]-.). \textit{Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]}. Heidelberg: Johan Ambrosius Barth Verlag, 1997, vol.~1997, No~623, p.~637-641. ISSN~0044-2313.
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