KANICKÝ, Viktor and Jean-Michel MERMET. Use of a single calibration graph for the determination of major elements in geological materials by laser ablation inductively coupled plasma atomic emission spectrometry with added internal standards. Fresenius Journal of Analytical Chemistry. Berlin: Springer-Verlag, 1999, vol. 363, No 3, p. 294-299. ISSN 0937-0633.
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Basic information
Original name Use of a single calibration graph for the determination of major elements in geological materials by laser ablation inductively coupled plasma atomic emission spectrometry with added internal standards
Authors KANICKÝ, Viktor (203 Czech Republic, guarantor) and Jean-Michel MERMET (250 France).
Edition Fresenius Journal of Analytical Chemistry, Berlin, Springer-Verlag, 1999, 0937-0633.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10406 Analytical chemistry
Country of publisher Germany
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 1.428
RIV identification code RIV/00216224:14310/99:00000870
Organization unit Faculty of Science
UT WoS 000078731000016
Keywords in English Laser ablation; Inductively coupled plasma atomic emission spectrometry; geology; silicates; carbonates; fused pellets; lithiummetaborate; internal standards
Tags carbonates, fused pellets, Geology, INTERNAL STANDARDS, laser ablation, lithiummetaborate, silicates
Tags International impact, Reviewed
Changed by Changed by: prof. RNDr. Viktor Kanický, DrSc., učo 408. Changed: 29/6/2007 10:01.
Abstract
The possibility of internal standardisation in laser ablation inductively coupled plasma atomic emission spectrometry (LA-ICP-AES) of geological materials by added Sc2O3 and Y2O3 has been examined to cover the wide range of concentrations of major and minor constituents both in silicate rocks and limestones. A Nd:YAG laser (355 nm, 10 Hz, 10 mJ per shot) was used for the ablation of discs obtained by fusion of the mixture of samples and oxides of Sc and Y with lithium tetraborate. The flux/sample ratio was in the range from 6 to 10. The contents of analytes were within the concentration range from hundredths to tens of percentage. The trace elements copper and nickel were studied, too. An ICP emission spectrometer OPTIMA 3000 DV was used for the measurement of Si, Al, Ca, Mg, Sr, Ba. Fe, Ti, Mn, Ni, Cu. Na and K analyte lines and Y and Sc reference lines in the axial observation mode. The long-term and the short-term repeatability of measurement were improved by employing scandium or yttrium internal references lines for the above analytes from 6% to 1.5% of RSD and from 2.4% to 1.0% of RSD, respectively. The correlation of signals with concentrations was improved in terms of the correlation coefficient r from 0.90-0.97 to 0.98-0.998 and the relative uncertainty on the centroid of concentrations was improved 2-3 times. A single calibration graph covering the concentration range both in silicates and carbonates is possible for each of elements. as the matrix effects are compensated for by internal standards and the excess of Li2B4O7.
Abstract (in Czech)
The possibility of internal standardisation in laser ablation inductively coupled plasma atomic emission spectrometry (LA-ICP-AES) of geological materials by added Sc2O3 and Y2O3 has been examined to cover the wide range of concentrations of major and minor constituents both in silicate rocks and limestones. A Nd:YAG laser (355 nm, 10 Hz, 10 mJ per shot) was used for the ablation of discs obtained by fusion of the mixture of samples and oxides of Sc and Y with lithium tetraborate. The flux/sample ratio was in the range from 6 to 10. The contents of analytes were within the concentration range from hundredths to tens of percentage. The trace elements copper and nickel were studied, too. An ICP emission spectrometer OPTIMA 3000 DV was used for the measurement of Si, Al, Ca, Mg, Sr, Ba. Fe, Ti, Mn, Ni, Cu. Na and K analyte lines and Y and Sc reference lines in the axial observation mode. The long-term and the short-term repeatability of measurement were improved by employing scandium or yttrium internal references lines for the above analytes from 6% to 1.5% of RSD and from 2.4% to 1.0% of RSD, respectively. The correlation of signals with concentrations was improved in terms of the correlation coefficient r from 0.90-0.97 to 0.98-0.998 and the relative uncertainty on the centroid of concentrations was improved 2-3 times. A single calibration graph covering the concentration range both in silicates and carbonates is possible for each of elements. as the matrix effects are compensated for by internal standards and the excess of Li2B4O7.
Links
GA203/94/0511, research and development projectName: Studium interakce laserového záření s deponovanými keramickými vrstvami.
Investor: Czech Science Foundation, Standard Projects
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