YANG, Y., M. G. WALAWALKAR, Jiří PINKAS, Herbert W. ROESKY and H. G. SCHMIDT. Molecular Aluminophosphonate: Model Compound for the Isoelectronic Double-Six-Ring (D6R) Secondary Building Unit of Zeolites. Angew. Chem. Int. Ed. Engl. Německo: Wiley-VCH Verlag GmbH, Weinheim, 1998, vol. 37, 1/2, p. 96-98. ISSN 0570-0833.
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Basic information
Original name Molecular Aluminophosphonate: Model Compound for the Isoelectronic Double-Six-Ring (D6R) Secondary Building Unit of Zeolites
Authors YANG, Y., M. G. WALAWALKAR, Jiří PINKAS, Herbert W. ROESKY and H. G. SCHMIDT.
Edition Angew. Chem. Int. Ed. Engl. Německo, Wiley-VCH Verlag GmbH, Weinheim, 1998, 0570-0833.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher Germany
Confidentiality degree is not subject to a state or trade secret
Organization unit Faculty of Science
Keywords in English aluminum; phosphonates; structure elucidation; zeolite analogues
Tags aluminum, phosphonates, structure elucidation, zeolite analogues
Changed by Changed by: prof. RNDr. Jiří Pinkas, Ph.D., učo 627. Changed: 14/8/2001 18:19.
Abstract
The reaction of tert-butylphosphonic acid with equimolar quantities of AlMe3 in THF/n-hexane yields a mixture of [MeAlO3PtBu]6 (1) and [MeAlO3PtBu]4 (2). The molecular structure of 1 resembles the D6R building units found in aluminophosphates. The central core of the Al6O18P6 polyhedron can be described as a cylindrical drum. By tailoring the alkyl groups on aluminum and phosphorus, it is possible to generate bigger building units of aluminophosphate molecular sieves.
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