PINKAS, Jiří and J. G. VERKADE. On the Reaction of P4S10 with Hexamethydisilazane. Heteroatom Chem. Spojené státy americké: John Wiley and Sons, New York, 1998, vol. 9, No 2, p. 115-121. ISSN 1042-7163.
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Basic information
Original name On the Reaction of P4S10 with Hexamethydisilazane
Authors PINKAS, Jiří and J. G. VERKADE.
Edition Heteroatom Chem. Spojené státy americké, John Wiley and Sons, New York, 1998, 1042-7163.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher United States of America
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 0.577
Organization unit Faculty of Science
Keywords in English phosphorus; sulfides; thiophosphoric acids
Tags Phosphorus, sulfides, thiophosphoric acids
Changed by Changed by: prof. RNDr. Jiří Pinkas, Ph.D., učo 627. Changed: 15/8/2001 10:14.
Abstract
P4S10 reacts with HMDSN to give SP(NHSiMe3)x(SSiME3)3-x where x = 0-3. These species were shown by 31P NMR spectroscopy to subsequently form cyclic and linear condensation products. The molecular structure of a linear trimer was authenticated by an X-ray diffraction study.
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