PINKAS, Jiří and J. G. VERKADE. Dimethylamino Gallatrane: Solution and Gas Phase Behavior. Polyhedron. Velká Británie: PERGAMON-ELSEVIER SCIENCE LTD, OXFORD, 1996, vol. 15, No 9, p. 1567-1569. ISSN 0277-5387.
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Basic information
Original name Dimethylamino Gallatrane: Solution and Gas Phase Behavior
Authors PINKAS, Jiří and J. G. VERKADE.
Edition Polyhedron, Velká Británie, PERGAMON-ELSEVIER SCIENCE LTD, OXFORD, 1996, 0277-5387.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
Organization unit Faculty of Science
Keywords in English tautomerism; gallium; atranes
Tags ATRANES, gallium, tautomerism
Changed by Changed by: prof. RNDr. Jiří Pinkas, Ph.D., učo 627. Changed: 15/8/2001 10:26.
Abstract
The gallatrane Ga(OCH2CH2)(3)N (1) forms a dimethylamine adduct, which exists in solutions in two tautomeric forms : a tricyclic cage, Me(2)NHGa(OCH2CH2)(3)N, and an open-cage bicyclic species Me(2)NGa(OCH2CH2)(2)NCH2CH2OH, which were identified by H-1, C-13 and Ga-71 NMR spectroscopy. The mass spectrum of the adduct revealed a homologous series of oligomers of 1(n), where n = 1, 2, 3 and 4.
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