New P-S-N containing ring systems. Reaction of
2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disu
lfide and its 4-methoxonaphthalene derivative with
hexamethyldisilazane.

J 1998

New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.

KILIÁN, Petr, Jaromír MAREK, Jiří TOUŽÍN, Otakar HUMPA, Josef NOVOSAD et. al.

Basic information

Original name

New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.

Authors

KILIÁN, Petr (203 Czech Republic), Jaromír MAREK (203 Czech Republic), Jiří TOUŽÍN (203 Czech Republic, guarantor), Otakar HUMPA (203 Czech Republic), Josef NOVOSAD (203 Czech Republic), J. D. WOOLLINNS (826 United Kingdom of Great Britain and Northern Ireland) and Radek MAREK (203 Czech Republic)

Edition

J. Chem. Soc. Dalton Trans. 1998, 0300-9246

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 2.507

RIV identification code

RIV/00216224:14310/98:00005903

Organization unit

Faculty of Science

Keywords in English

X-RAY STRUCTURE; NMR

Abstract

V originále

Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1 with hexamethyldisilazane (hmds) in acetonitrile gave the N,N'-bis(trimethylsilyl)acetamidinium salt of the [(C10H6)P(S)(NHSiMe3)SP(S)(2)](-) anion 2, a product of P,S, ring cleavage, together with the new thiazaphosphetidine (C10H6)P(S)SN(SiMe3)P(S) 3. Analogous (methoxy derived) products to 2 (2a, 2b) and 3 (3a) were obtained when 2,4-(4-methoxynaphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1a was used instead of 1. When the reaction of 1 with hmds was performed in dichloromethane a mixture of the products was obtained, from which the hexamethyldisilazan-2-ium salt of the anion of identical structure to that in 2 has been isolated. No reaction occurred when a solventless system was used. The new compounds were studied spectroscopically (one-and two-dimensional NMR, IR spectroscopy) and by X-ray crystallography (3, 3a and 4).

Links

GA203/97/0955, research and development project

Name: Studium syntézy, struktury a vazebných poměrů ve sloučeninách obsahujících současně dusík, fosfor, chalkogen a/nebo halogen

Investor: Czech Science Foundation, Synthesis ,structure and bonding of compounds containing phosphorus,nitrogen,chalcogene and/or halogene atoms

Citovat

KILIÁN, Petr, Jaromír MAREK, Jiří TOUŽÍN, Otakar HUMPA, Josef NOVOSAD, J. D. WOOLLINNS and Radek MAREK. New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane. (: New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.). J. Chem. Soc. Dalton Trans. 1998, vol. 1998, No 7, p. 1175-1180. ISSN 0300-9246.

@article{211971,
   author = {Kilián, Petr and Marek, Jaromír and Toužín, Jiří and Humpa, Otakar and Novosad, Josef and Woollinns, J. D. and Marek, Radek},
   article_number = {7},
   keywords = {X-RAY STRUCTURE; NMR},
   language = {eng},
   issn = {0300-9246},
   journal = {J. Chem. Soc. Dalton Trans.},
   title = {New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.},
   volume = {1998},
   year = {1998}
}

TY  - JOUR
ID  - 211971
AU  - Kilián, Petr - Marek, Jaromír - Toužín, Jiří - Humpa, Otakar - Novosad, Josef - Woollinns, J. D. - Marek, Radek
PY  - 1998
TI  - New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.
JF  - J. Chem. Soc. Dalton Trans.
VL  - 1998
IS  - 7
SP  - 1175
EP  - 1175
SN  - 03009246
KW  - X-RAY STRUCTURE
KW  - NMR
N2  - Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1 with hexamethyldisilazane (hmds) in acetonitrile gave the N,N'-bis(trimethylsilyl)acetamidinium salt of the [(C10H6)P(S)(NHSiMe3)SP(S)(2)](-) anion 2, a product of P,S, ring cleavage, together with the new thiazaphosphetidine (C10H6)P(S)SN(SiMe3)P(S) 3. Analogous (methoxy derived) products to 2 (2a, 2b) and 3 (3a) were obtained when 2,4-(4-methoxynaphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide 1a was used instead of 1. When the reaction of 1 with hmds was performed in dichloromethane a mixture of the products was obtained, from which the hexamethyldisilazan-2-ium salt of the anion of identical structure to that in 2 has been isolated. No reaction occurred when a solventless system was used. The new compounds were studied spectroscopically (one-and two-dimensional NMR, IR spectroscopy) and by X-ray crystallography (3, 3a and 4).
ER  -

KILIÁN, Petr, Jaromír MAREK, Jiří TOUŽÍN, Otakar HUMPA, Josef NOVOSAD, J. D. WOOLLINNS and Radek MAREK. New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane. (: New P-S-N containing ring systems. Reaction of 2,4-(naphthalene-1,8-diyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide and its 4-methoxonaphthalene derivative with hexamethyldisilazane.). \textit{J. Chem. Soc. Dalton Trans.}. 1998, vol.~1998, No~7, p.~1175-1180. ISSN~0300-9246.

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