Detailed Information on Publication Record
1999
The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry
KLÁN, Petr, Jaromír LITERÁK and Milan HÁJEKBasic information
Original name
The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry
Authors
KLÁN, Petr (203 Czech Republic, guarantor), Jaromír LITERÁK (203 Czech Republic) and Milan HÁJEK
Edition
Journal of Photochemistry and Photobiology A: Chemistry, Amsterdam, The Netherlands, Elsevier Science, 1999, 1010-6030
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10401 Organic chemistry
Country of publisher
Netherlands
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 1.034
RIV identification code
RIV/00216224:14310/99:00001184
Organization unit
Faculty of Science
UT WoS
000083774300019
Keywords (in Czech)
Fotochemie
Keywords in English
Photochemistry
Tags
Změněno: 7/4/2010 18:29, Mgr. Jaromír Literák, Ph.D.
V originále
A simple photochemical reactor has been developed and tested for photochemical reactions. It consisted of an electrodeless discharge lamp (MWL) placed into the reactor vessel of a commercial microwave oven. The microwave (MW) field generated ultraviolet irradiation by the lamp at the same time as it interacted with a studied sample. This technique brings a unique possibility to study the simultaneous effect of both UV/VIS and MW irradiations on photochemical reactions. The use of MWL in a MW reactor has been studied in terms of (1) an operating MW power and temperature influence on the lamp, (2) solvent polarity influence, (3) MWL heating capabilities, and (4) dependence of the photoreaction efficiency on the MW power output. It was found that the lamp produced enough heat to quickly warm up any liquid to boil even in case of 'transparent' liquids in the MW field. An efficiency of light-induced photofragmentation reaction of valerophenone (Type II reaction) was investigated.
In Czech
A simple photochemical reactor has been developed and tested for photochemical reactions. It consisted of an electrodeless discharge lamp (MWL) placed into the reactor vessel of a commercial microwave oven. The microwave (MW) field generated ultraviolet irradiation by the lamp at the same time as it interacted with a studied sample. This technique brings a unique possibility to study the simultaneous effect of both UV/VIS and MW irradiations on photochemical reactions. The use of MWL in a MW reactor has been studied in terms of (1) an operating MW power and temperature influence on the lamp, (2) solvent polarity influence, (3) MWL heating capabilities, and (4) dependence of the photoreaction efficiency on the MW power output. It was found that the lamp produced enough heat to quickly warm up any liquid to boil even in case of 'transparent' liquids in the MW field. An efficiency of light-induced photofragmentation reaction of valerophenone (Type II reaction) was investigated.
Links
| MSM 143100011, plan (intention) |
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