DE SIMONE, Nicola Alessandro, Matúš CHVOJKA, Jana LAPEŠOVÁ, Luis MARTÍNEZ-CRESPO, Petr SLÁVIK, Jan SOKOLOV, Stephen J. BUTLER, Hennie VALKENIER and Vladimír ŠINDELÁŘ. Monofunctionalized Fluorinated Bambusurils and Their Conjugates for Anion Transport and Extraction. Journal of Organic Chemistry. American Chemical Society, 2022, vol. 87, No 15, p. 9829-9838. ISSN 0022-3263. Available from: https://dx.doi.org/10.1021/acs.joc.2c00870.
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Basic information
Original name Monofunctionalized Fluorinated Bambusurils and Their Conjugates for Anion Transport and Extraction
Authors DE SIMONE, Nicola Alessandro (380 Italy, belonging to the institution), Matúš CHVOJKA (703 Slovakia, belonging to the institution), Jana LAPEŠOVÁ (203 Czech Republic, belonging to the institution), Luis MARTÍNEZ-CRESPO, Petr SLÁVIK (203 Czech Republic, belonging to the institution), Jan SOKOLOV (203 Czech Republic, belonging to the institution), Stephen J. BUTLER, Hennie VALKENIER and Vladimír ŠINDELÁŘ (203 Czech Republic, guarantor, belonging to the institution).
Edition Journal of Organic Chemistry, American Chemical Society, 2022, 0022-3263.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10400 1.4 Chemical sciences
Country of publisher United States of America
Confidentiality degree is not subject to a state or trade secret
WWW URL
Impact factor Impact factor: 3.600
RIV identification code RIV/00216224:14310/22:00126597
Organization unit Faculty of Science
Doi http://dx.doi.org/10.1021/acs.joc.2c00870
UT WoS 000886435300001
Keywords in English Anions; Assays; Extraction; Macrocycles; Reaction products
Tags CF PROT, rivok
Tags International impact, Reviewed
Changed by Changed by: Mgr. Marie Šípková, DiS., učo 437722. Changed: 31/1/2023 08:51.
Abstract
Bambusurils are macrocyclic molecules that are known for their high binding affinity and selectivity toward anions. Here, we present the preparation of two bambusurils bearing fluorinated substituents and one carboxylic function. These monofunctionalized bambusurils were conjugated with crown ether and cholesterol units. The resulting conjugates were successfully tested in liquid–liquid extraction of inorganic salts and chloride/bicarbonate transport across lipid bilayers.
Links
EF17_043/0009632, research and development projectName: CETOCOEN Excellence
GA20-13922S, research and development projectName: Monofunkcializované bambusurily a jejich supramolekulární vlastnosti
Investor: Czech Science Foundation
LM2018121, research and development projectName: Výzkumná infrastruktura RECETOX (Acronym: RECETOX RI)
Investor: Ministry of Education, Youth and Sports of the CR, RECETOX RI
LM2018127, research and development projectName: Česká infrastruktura pro integrativní strukturní biologii (Acronym: CIISB)
Investor: Ministry of Education, Youth and Sports of the CR
857560, interní kód MU
(CEP code: EF17_043/0009632)
Name: CETOCOEN Excellence (Acronym: CETOCOEN Excellence)
Investor: European Union, Spreading excellence and widening participation
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