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@inbook{2245937,
author = {Otevřel, Jan and Waser, Mario},
address = {Weinheim, Germany},
booktitle = {Asymmetric Organocatalysis: New Strategies, Catalysts, and Opportunities},
doi = {http://dx.doi.org/10.1002/9783527832217.ch3},
edition = {1.},
editor = {Łukasz Albrecht, Anna Albrecht, Luca Dell'Amico},
keywords = {Phase-Transfer Catalysis; Ion-Pairing Catalysis; Organocatalysis},
howpublished = {tištěná verze "print"},
language = {eng},
location = {Weinheim, Germany},
isbn = {978-3-527-83221-7},
pages = {71-120},
publisher = {WILEY‐VCH GmbH},
title = {Asymmetric Phase-Transfer Catalysis - From Classical Applications to New Concepts},
url = {https://onlinelibrary.wiley.com/doi/10.1002/9783527832217.ch3},
year = {2022}
}
TY - CHAP
ID - 2245937
AU - Otevřel, Jan - Waser, Mario
PY - 2022
TI - Asymmetric Phase-Transfer Catalysis - From Classical Applications to New Concepts
VL - 1. vydání
PB - WILEY‐VCH GmbH
CY - Weinheim, Germany
SN - 9783527832217
KW - Phase-Transfer Catalysis
KW - Ion-Pairing Catalysis
KW - Organocatalysis
UR - https://onlinelibrary.wiley.com/doi/10.1002/9783527832217.ch3
N2 - Asymmetric (ion-pairing) phase-transfer catalysis has emerged as a powerful concept within the realm of asymmetric (organo)-catalysis over the course of the last four decades. Whereas early approaches mainly focused around the use of chiral ammonium salt catalysts for the control of enolate-type nucleophiles, the last years have witnessed a remarkable diversity of novel catalyst motives and new applications, reaching beyond what was classically considered as phase-transfer catalysis. As a consequence, a strict mechanistic classification of whether a reaction is really a phase-transfer-catalyzed process or not is also often not so easily possible anymore, underscoring the diversity of this field. Within this chapter, we wish to highlight the unique potential of chiral cationic, anionic, and neutral phase-transfer catalysts (PTCs) to facilitate challenging target transformations by discussing some of the, in our opinion, most important catalyst classes and applications thereof, with a special focus on some of the most recently introduced concepts.
ER -
OTEVŘEL, Jan and Mario WASER. Asymmetric Phase-Transfer Catalysis - From Classical Applications to New Concepts. In Łukasz Albrecht, Anna Albrecht, Luca Dell'Amico. \textit{Asymmetric Organocatalysis: New Strategies, Catalysts, and Opportunities}. 1st ed. Weinheim, Germany: WILEY‐VCH GmbH, 2022, p.~71-120. 1. vydání. ISBN~978-3-527-83221-7. Available from: https://dx.doi.org/10.1002/9783527832217.ch3.
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