Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D
Germanane Heterostructures via Click Chemistry

J 2022

Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry

MUNOZ, Jose, Mario PALACIOS-CORELLA, Inmaculada Jennifer GOMEZ PEREZ, Lenka ZAJÍČKOVÁ, Martin PUMERA et. al.

Basic information

Original name

Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry

Authors

MUNOZ, Jose, Mario PALACIOS-CORELLA, Inmaculada Jennifer GOMEZ PEREZ (724 Spain, belonging to the institution), Lenka ZAJÍČKOVÁ (203 Czech Republic, belonging to the institution) and Martin PUMERA (guarantor)

Edition

Advanced Materials, Wiley-VCH Verlag GmbH, 2022, 0935-9648

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10405 Electrochemistry

Country of publisher

Germany

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 29.400

RIV identification code

RIV/00216224:14310/22:00128051

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1002/adma.202206382

UT WoS

000865568200001

Keywords in English

2D materials; carbon dots; fluorescence resonance energy transfer; optoelectronics; thiol-ene

Abstract

V originále

ucceeding graphene, 2D inorganic materials made of reactive van der Waals layers, like 2D germanane (2D-Ge) derivatives, have attracted great attention because their physicochemical characteristics can be entirely tuned by modulating the nature of the surface substituent. Although very interesting from a scientific point of view, almost all the reported works involving 2D-Ge derivatives are focused on computational studies. Herein, a first prototype of organic–inorganic 2D-Ge heterostructure has been synthesized by covalently anchoring thiol-rich carbon dots (CD–SH) onto 2D allyl germanane (2D-aGe) via a simple and green “one-pot” click chemistry approach. Remarkably, the implanted characteristics of the carbon nanomaterial provide new physicochemical features to the resulting 0D/2D heterostructure, making possible its implementation in yet unexplored optoelectronic tasks—e.g., as a fluorescence resonance energy transfer (FRET) sensing system triggered by supramolecular π–π interactions—that are inaccessible for the pristine 2D-aGe counterpart. Consequently, this work builds a foundation toward the robust achievement of functional organic–inorganic 2D-Ge nanoarchitectonics through covalently assembling thiol-rich carbon nanoallotropes on commercially available 2D-aGe.

Links

EF20_079/0017045, research and development project

Name: MSCAfellow4@MUNI

90110, large research infrastructures

Name: CzechNanoLab

Citovat

MUNOZ, Jose, Mario PALACIOS-CORELLA, Inmaculada Jennifer GOMEZ PEREZ, Lenka ZAJÍČKOVÁ and Martin PUMERA. Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry. Advanced Materials. Wiley-VCH Verlag GmbH, 2022, vol. 34, No 45, p. 1-8. ISSN 0935-9648. Available from: https://dx.doi.org/10.1002/adma.202206382.

@article{2247374,
   author = {Munoz, Jose and PalaciosandCorella, Mario and Gomez Perez, Inmaculada Jennifer and Zajíčková, Lenka and Pumera, Martin},
   article_number = {45},
   doi = {http://dx.doi.org/10.1002/adma.202206382},
   keywords = {2D materials; carbon dots; fluorescence resonance energy transfer; optoelectronics; thiol-ene},
   language = {eng},
   issn = {0935-9648},
   journal = {Advanced Materials},
   title = {Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry},
   url = {https://doi.org/10.1002/adma.202206382},
   volume = {34},
   year = {2022}
}

TY  - JOUR
ID  - 2247374
AU  - Munoz, Jose - Palacios-Corella, Mario - Gomez Perez, Inmaculada Jennifer - Zajíčková, Lenka - Pumera, Martin
PY  - 2022
TI  - Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry
JF  - Advanced Materials
VL  - 34
IS  - 45
SP  - 1-8
EP  - 1-8
PB  - Wiley-VCH Verlag GmbH
SN  - 09359648
KW  - 2D materials
KW  - carbon dots
KW  - fluorescence resonance energy transfer
KW  - optoelectronics
KW  - thiol-ene
UR  - https://doi.org/10.1002/adma.202206382
N2  - ucceeding graphene, 2D inorganic materials made of reactive van der Waals layers, like 2D germanane (2D-Ge) derivatives, have attracted great attention because their physicochemical characteristics can be entirely tuned by modulating the nature of the surface substituent. Although very interesting from a scientific point of view, almost all the reported works involving 2D-Ge derivatives are focused on computational studies. Herein, a first prototype of organic–inorganic 2D-Ge heterostructure has been synthesized by covalently anchoring thiol-rich carbon dots (CD–SH) onto 2D allyl germanane (2D-aGe) via a simple and green “one-pot” click chemistry approach. Remarkably, the implanted characteristics of the carbon nanomaterial provide new physicochemical features to the resulting 0D/2D heterostructure, making possible its implementation in yet unexplored optoelectronic tasks—e.g., as a fluorescence resonance energy transfer (FRET) sensing system triggered by supramolecular π–π interactions—that are inaccessible for the pristine 2D-aGe counterpart. Consequently, this work builds a foundation toward the robust achievement of functional organic–inorganic 2D-Ge nanoarchitectonics through covalently assembling thiol-rich carbon nanoallotropes on commercially available 2D-aGe.
ER  -

MUNOZ, Jose, Mario PALACIOS-CORELLA, Inmaculada Jennifer GOMEZ PEREZ, Lenka ZAJÍČKOVÁ and Martin PUMERA. Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry. \textit{Advanced Materials}. Wiley-VCH Verlag GmbH, 2022, vol.~34, No~45, p.~1-8. ISSN~0935-9648. Available from: https://dx.doi.org/10.1002/adma.202206382.

Detailed Information on Publication Record