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@article{2247374,
author = {Munoz, Jose and PalaciosandCorella, Mario and Gomez Perez, Inmaculada Jennifer and Zajíčková, Lenka and Pumera, Martin},
article_number = {45},
doi = {http://dx.doi.org/10.1002/adma.202206382},
keywords = {2D materials; carbon dots; fluorescence resonance energy transfer; optoelectronics; thiol-ene},
language = {eng},
issn = {0935-9648},
journal = {Advanced Materials},
title = {Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry},
url = {https://doi.org/10.1002/adma.202206382},
volume = {34},
year = {2022}
}
TY - JOUR
ID - 2247374
AU - Munoz, Jose - Palacios-Corella, Mario - Gomez Perez, Inmaculada Jennifer - Zajíčková, Lenka - Pumera, Martin
PY - 2022
TI - Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry
JF - Advanced Materials
VL - 34
IS - 45
SP - 1-8
EP - 1-8
PB - Wiley-VCH Verlag GmbH
SN - 09359648
KW - 2D materials
KW - carbon dots
KW - fluorescence resonance energy transfer
KW - optoelectronics
KW - thiol-ene
UR - https://doi.org/10.1002/adma.202206382
N2 - ucceeding graphene, 2D inorganic materials made of reactive van der Waals layers, like 2D germanane (2D-Ge) derivatives, have attracted great attention because their physicochemical characteristics can be entirely tuned by modulating the nature of the surface substituent. Although very interesting from a scientific point of view, almost all the reported works involving 2D-Ge derivatives are focused on computational studies. Herein, a first prototype of organic–inorganic 2D-Ge heterostructure has been synthesized by covalently anchoring thiol-rich carbon dots (CD–SH) onto 2D allyl germanane (2D-aGe) via a simple and green “one-pot” click chemistry approach. Remarkably, the implanted characteristics of the carbon nanomaterial provide new physicochemical features to the resulting 0D/2D heterostructure, making possible its implementation in yet unexplored optoelectronic tasks—e.g., as a fluorescence resonance energy transfer (FRET) sensing system triggered by supramolecular π–π interactions—that are inaccessible for the pristine 2D-aGe counterpart. Consequently, this work builds a foundation toward the robust achievement of functional organic–inorganic 2D-Ge nanoarchitectonics through covalently assembling thiol-rich carbon nanoallotropes on commercially available 2D-aGe.
ER -
MUNOZ, Jose, Mario PALACIOS-CORELLA, Inmaculada Jennifer GOMEZ PEREZ, Lenka ZAJÍČKOVÁ and Martin PUMERA. Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry. \textit{Advanced Materials}. Wiley-VCH Verlag GmbH, 2022, vol.~34, No~45, p.~1-8. ISSN~0935-9648. Available from: https://dx.doi.org/10.1002/adma.202206382.
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