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@article{2247374, author = {Munoz, Jose and PalaciosandCorella, Mario and Gomez Perez, Inmaculada Jennifer and Zajíčková, Lenka and Pumera, Martin}, article_number = {45}, doi = {http://dx.doi.org/10.1002/adma.202206382}, keywords = {2D materials; carbon dots; fluorescence resonance energy transfer; optoelectronics; thiol-ene}, language = {eng}, issn = {0935-9648}, journal = {Advanced Materials}, title = {Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry}, url = {https://doi.org/10.1002/adma.202206382}, volume = {34}, year = {2022} }
TY - JOUR ID - 2247374 AU - Munoz, Jose - Palacios-Corella, Mario - Gomez Perez, Inmaculada Jennifer - Zajíčková, Lenka - Pumera, Martin PY - 2022 TI - Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry JF - Advanced Materials VL - 34 IS - 45 SP - 1-8 EP - 1-8 PB - Wiley-VCH Verlag GmbH SN - 09359648 KW - 2D materials KW - carbon dots KW - fluorescence resonance energy transfer KW - optoelectronics KW - thiol-ene UR - https://doi.org/10.1002/adma.202206382 N2 - ucceeding graphene, 2D inorganic materials made of reactive van der Waals layers, like 2D germanane (2D-Ge) derivatives, have attracted great attention because their physicochemical characteristics can be entirely tuned by modulating the nature of the surface substituent. Although very interesting from a scientific point of view, almost all the reported works involving 2D-Ge derivatives are focused on computational studies. Herein, a first prototype of organic–inorganic 2D-Ge heterostructure has been synthesized by covalently anchoring thiol-rich carbon dots (CD–SH) onto 2D allyl germanane (2D-aGe) via a simple and green “one-pot” click chemistry approach. Remarkably, the implanted characteristics of the carbon nanomaterial provide new physicochemical features to the resulting 0D/2D heterostructure, making possible its implementation in yet unexplored optoelectronic tasks—e.g., as a fluorescence resonance energy transfer (FRET) sensing system triggered by supramolecular π–π interactions—that are inaccessible for the pristine 2D-aGe counterpart. Consequently, this work builds a foundation toward the robust achievement of functional organic–inorganic 2D-Ge nanoarchitectonics through covalently assembling thiol-rich carbon nanoallotropes on commercially available 2D-aGe. ER -
MUNOZ, Jose, Mario PALACIOS-CORELLA, Inmaculada Jennifer GOMEZ PEREZ, Lenka ZAJÍČKOVÁ and Martin PUMERA. Synthetic Nanoarchitectonics of Functional Organic-Inorganic 2D Germanane Heterostructures via Click Chemistry. \textit{Advanced Materials}. Wiley-VCH Verlag GmbH, 2022, vol.~34, No~45, p.~1-8. ISSN~0935-9648. Available from: https://dx.doi.org/10.1002/adma.202206382.
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