Other formats:
BibTeX
LaTeX
RIS
@article{2254007,
author = {Chyba, Jan and Hruzíková, Anna and Knor, Michal and Pikulová, Petra and Marková, Kateřina and Novotný, Jan and Marek, Radek},
article_number = {8},
doi = {http://dx.doi.org/10.1021/acs.inorgchem.2c03282},
keywords = {NMR spectroscopy;hyperfine interaction;ruthenium(III);relativistic DFT;stability},
language = {eng},
issn = {0020-1669},
journal = {Inorganic Chemistry},
title = {Nature of NMR Shifts in Paramagnetic Octahedral Ru(III) Complexes with Axial Pyridine-Based Ligands},
url = {http://dx.doi.org/10.1021/acs.inorgchem.2c03282},
volume = {62},
year = {2023}
}
TY - JOUR
ID - 2254007
AU - Chyba, Jan - Hruzíková, Anna - Knor, Michal - Pikulová, Petra - Marková, Kateřina - Novotný, Jan - Marek, Radek
PY - 2023
TI - Nature of NMR Shifts in Paramagnetic Octahedral Ru(III) Complexes with Axial Pyridine-Based Ligands
JF - Inorganic Chemistry
VL - 62
IS - 8
SP - 3381-3394
EP - 3381-3394
PB - American Chemical Society
SN - 00201669
KW - NMR spectroscopy;hyperfine interaction;ruthenium(III);relativistic DFT;stability
UR - http://dx.doi.org/10.1021/acs.inorgchem.2c03282
N2 - In recent decades, transition-metal coordination compounds have been extensively studied for their antitumor and antimetastatic activities. In this work, we synthesized a set of symmetric and asymmetric Ru(III) and Rh(III) coordination compounds of the general structure (Na+/K+/PPh4+/LH+) [trans-M(III)L(eq)nL(ax)2]- (M = Ru(III) or Rh(III); L(eq) = Cl, n = 4; L(eq) = ox, n = 2; L(ax) = 4-R-pyridine, R = CH3, H, C6H5, COOH, CF3, CN; L(ax) = DMSO-S) and systematically investigated their structure, stability, and NMR properties. 1H and 13C NMR spectra measured at various temperatures were used to break down the total NMR shifts into the orbital (temperature independent) and hyperfine (temperature dependent) contributions. The hyperfine NMR shifts for paramagnetic Ru(III) compounds were analyzed in detail by using relativistic density-functional theory (DFT). The effects of i) the 4-R substituent of pyridine, ii) the axial trans ligand L(ax), and iii) the equatorial ligands L(eq) on the distribution of spin density reflected in the “through-bond” (contact) and the “through-space” (pseudocontact) contributions to the hyperfine NMR shifts of the individual atoms of the pyridine ligands are rationalized. Further, we demonstrate the large effects of the solvent on the hyperfine NMR shifts and discuss our observations in the general context of the paramagnetic NMR spectroscopy of transition-metal complexes.
ER -
CHYBA, Jan, Anna HRUZÍKOVÁ, Michal KNOR, Petra PIKULOVÁ, Kateřina MARKOVÁ, Jan NOVOTNÝ and Radek MAREK. Nature of NMR Shifts in Paramagnetic Octahedral Ru(III) Complexes with Axial Pyridine-Based Ligands. \textit{Inorganic Chemistry}. American Chemical Society, 2023, vol.~62, No~8, p.~3381-3394. ISSN~0020-1669. Available from: https://dx.doi.org/10.1021/acs.inorgchem.2c03282.
|
