One-step synthesis of gold nanoparticles for catalysis and SERS
applications using selectively dicarboxylated cellulose and
hyaluronate

J 2022

One-step synthesis of gold nanoparticles for catalysis and SERS applications using selectively dicarboxylated cellulose and hyaluronate

VAVROVA, Alzbeta, Tereza CAPKOVA, Ivo KURITKA, Jan VICHA, Lukas MUNSTER et. al.

Basic information

Original name

One-step synthesis of gold nanoparticles for catalysis and SERS applications using selectively dicarboxylated cellulose and hyaluronate

Authors

VAVROVA, Alzbeta, Tereza CAPKOVA, Ivo KURITKA, Jan VICHA and Lukas MUNSTER

Edition

International journal of biological macromolecules, AMSTERDAM, Elsevier Science BV, Netherlands, 2022, 0141-8130

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10608 Biochemistry and molecular biology

Country of publisher

Netherlands

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 8.200

RIV identification code

RIV/00216224:14740/22:00128762

Organization unit

Central European Institute of Technology

DOI

http://dx.doi.org/10.1016/j.ijbiomac.2022.03.043

UT WoS

000795917600007

Keywords in English

Dicarboxypolysaccharides; Dicarboxylated cellulose; Dicarboxylated hyaluronate; Gold nanoparticles; Surface-enhanced Raman scattering; Catalysis

Abstract

V originále

Properties and applications of gold nanoparticles (AuNPs) depend on their characteristics which are intrinsically connected to the reducing and capping agents used in their synthesis. Although polysaccharides are commonly used for Au salt reduction, the control over the result is often limited. Here, the selectively dicarboxylated cellulose (DCC) and hyaluronate (DCH) with adjustable composition and molecular weight are used for the first time as reducing and capping agents for AuNPs preparation in an environmental friendly one-step synthesis. Mechanism of reduction and structure-function relationships between the composition of oxidized poly-saccharides and properties of formed AuNPs are elucidated and the variances in the macromolecular architecture of dicarboxypolysaccharides are applied to guide the growth of AuNPs. While the homogenous structure and high density of carboxyl groups of fully-oxidized DCC induced isotropic growth of small and uniform AuNPs with good catalytic performance (d =-20 nm, TOF = 7.3 min(-1), k = 1.47 min(-1)), the lower stabilizing potential and slower reduction rates of the DCH induced the anisotropic growth of larger polyhedral -50 nm nanoparticles, which increased the Surface-Enhanced Raman Scattering efficacy (9x stronger Raman signals on average compared to AuDCC). The use of dicarboxypolysaccharides with adjustable composition and properties thus introduced a new degree of freedom for the preparation of AuNPs with desired properties.

Links

90127, large research infrastructures

Name: CIISB II

Citovat

VAVROVA, Alzbeta, Tereza CAPKOVA, Ivo KURITKA, Jan VICHA and Lukas MUNSTER. One-step synthesis of gold nanoparticles for catalysis and SERS applications using selectively dicarboxylated cellulose and hyaluronate. International journal of biological macromolecules. AMSTERDAM: Elsevier Science BV, Netherlands, 2022, vol. 206, MAY, p. 927-938. ISSN 0141-8130. Available from: https://dx.doi.org/10.1016/j.ijbiomac.2022.03.043.

@article{2262415,
   author = {Vavrova, Alzbeta and Capkova, Tereza and Kuritka, Ivo and Vicha, Jan and Munster, Lukas},
   article_location = {AMSTERDAM},
   article_number = {MAY},
   doi = {http://dx.doi.org/10.1016/j.ijbiomac.2022.03.043},
   keywords = {Dicarboxypolysaccharides; Dicarboxylated cellulose; Dicarboxylated hyaluronate; Gold nanoparticles; Surface-enhanced Raman scattering; Catalysis},
   language = {eng},
   issn = {0141-8130},
   journal = {International journal of biological macromolecules},
   title = {One-step synthesis of gold nanoparticles for catalysis and SERS applications using selectively dicarboxylated cellulose and hyaluronate},
   url = {https://www.sciencedirect.com/science/article/pii/S0141813022005098?via%3Dihub},
   volume = {206},
   year = {2022}
}

TY  - JOUR
ID  - 2262415
AU  - Vavrova, Alzbeta - Capkova, Tereza - Kuritka, Ivo - Vicha, Jan - Munster, Lukas
PY  - 2022
TI  - One-step synthesis of gold nanoparticles for catalysis and SERS applications using selectively dicarboxylated cellulose and hyaluronate
JF  - International journal of biological macromolecules
VL  - 206
IS  - MAY
SP  - 927-938
EP  - 927-938
PB  - Elsevier Science BV, Netherlands
SN  - 01418130
KW  - Dicarboxypolysaccharides
KW  - Dicarboxylated cellulose
KW  - Dicarboxylated hyaluronate
KW  - Gold nanoparticles
KW  - Surface-enhanced Raman scattering
KW  - Catalysis
UR  - https://www.sciencedirect.com/science/article/pii/S0141813022005098?via%3Dihub
N2  - Properties and applications of gold nanoparticles (AuNPs) depend on their characteristics which are intrinsically connected to the reducing and capping agents used in their synthesis. Although polysaccharides are commonly used for Au salt reduction, the control over the result is often limited. Here, the selectively dicarboxylated cellulose (DCC) and hyaluronate (DCH) with adjustable composition and molecular weight are used for the first time as reducing and capping agents for AuNPs preparation in an environmental friendly one-step synthesis. Mechanism of reduction and structure-function relationships between the composition of oxidized poly-saccharides and properties of formed AuNPs are elucidated and the variances in the macromolecular architecture of dicarboxypolysaccharides are applied to guide the growth of AuNPs. While the homogenous structure and high density of carboxyl groups of fully-oxidized DCC induced isotropic growth of small and uniform AuNPs with good catalytic performance (d =-20 nm, TOF = 7.3 min(-1), k = 1.47 min(-1)), the lower stabilizing potential and slower reduction rates of the DCH induced the anisotropic growth of larger polyhedral -50 nm nanoparticles, which increased the Surface-Enhanced Raman Scattering efficacy (9x stronger Raman signals on average compared to AuDCC). The use of dicarboxypolysaccharides with adjustable composition and properties thus introduced a new degree of freedom for the preparation of AuNPs with desired properties.
ER  -

VAVROVA, Alzbeta, Tereza CAPKOVA, Ivo KURITKA, Jan VICHA and Lukas MUNSTER. One-step synthesis of gold nanoparticles for catalysis and SERS applications using selectively dicarboxylated cellulose and hyaluronate. \textit{International journal of biological macromolecules}. AMSTERDAM: Elsevier Science BV, Netherlands, 2022, vol.~206, MAY, p.~927-938. ISSN~0141-8130. Available from: https://dx.doi.org/10.1016/j.ijbiomac.2022.03.043.

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