MARTÍNEK, Marek, Lucie LUDVÍKOVÁ, Mária ŠRANKOVÁ, Rafael NAVRÁTIL, Lucie MUCHOVÁ, Jiří HUZLÍK, Libor VÍTEK, Petr KLÁN and Peter ŠEBEJ. Common xanthene fluorescent dyes are visible-light activatable CO-releasing molecules. Organic and Biomolecular Chemistry. Royal Society of Chemistry, 2023, vol. 21, No 1, p. 93-97. ISSN 1477-0520. Available from: https://dx.doi.org/10.1039/d2ob01823c. |
Other formats:
BibTeX
LaTeX
RIS
@article{2285197, author = {Martínek, Marek and Ludvíková, Lucie and Šranková, Mária and Navrátil, Rafael and Muchová, Lucie and Huzlík, Jiří and Vítek, Libor and Klán, Petr and Šebej, Peter}, article_number = {1}, doi = {http://dx.doi.org/10.1039/d2ob01823c}, keywords = {CARBON-MONOXIDE; QUANTUM YIELD; EOSIN-Y; PHOTOCHEMISTRY; OXYGEN; PHOTODEGRADATION; ANGIOGRAPHY; MECHANISM}, language = {eng}, issn = {1477-0520}, journal = {Organic and Biomolecular Chemistry}, title = {Common xanthene fluorescent dyes are visible-light activatable CO-releasing molecules}, url = {https://pubs.rsc.org/en/content/articlelanding/2023/OB/D2OB01823C}, volume = {21}, year = {2023} }
TY - JOUR ID - 2285197 AU - Martínek, Marek - Ludvíková, Lucie - Šranková, Mária - Navrátil, Rafael - Muchová, Lucie - Huzlík, Jiří - Vítek, Libor - Klán, Petr - Šebej, Peter PY - 2023 TI - Common xanthene fluorescent dyes are visible-light activatable CO-releasing molecules JF - Organic and Biomolecular Chemistry VL - 21 IS - 1 SP - 93-97 EP - 93-97 PB - Royal Society of Chemistry SN - 14770520 KW - CARBON-MONOXIDE KW - QUANTUM YIELD KW - EOSIN-Y KW - PHOTOCHEMISTRY KW - OXYGEN KW - PHOTODEGRADATION KW - ANGIOGRAPHY KW - MECHANISM UR - https://pubs.rsc.org/en/content/articlelanding/2023/OB/D2OB01823C N2 - Fluorescein, eosin Y, and rose bengal are dyes used in clinical medicine and considered (photo-)chemically stable. Upon extensive irradiation with visible light in aqueous solutions, we found that these compounds release carbon monoxide (CO) - a bioactive gasotransmitter - in 40-100% yields along with the production of low-mass secondary photoproducts, such as phthalic and formic acids, in a multistep degradation process. Such photochemistry should be considered in applications of these dyes, and they could also be utilized as visible-light activatable CO-releasing molecules (photoCORMs) with biological implications. ER -
MARTÍNEK, Marek, Lucie LUDVÍKOVÁ, Mária ŠRANKOVÁ, Rafael NAVRÁTIL, Lucie MUCHOVÁ, Jiří HUZLÍK, Libor VÍTEK, Petr KLÁN and Peter ŠEBEJ. Common xanthene fluorescent dyes are visible-light activatable CO-releasing molecules. \textit{Organic and Biomolecular Chemistry}. Royal Society of Chemistry, 2023, vol.~21, No~1, p.~93-97. ISSN~1477-0520. Available from: https://dx.doi.org/10.1039/d2ob01823c.
|