Laser ablation synthesis of tellurium carbides using tellurium
with nanodiamond nanocomposite

J 2023

Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite

CHYGORIN, Eduard, Lukáš PEČINKA, Petr VAŇHARA, Karel NOVOTNÝ, Ivo KREMPL et. al.

Basic information

Original name

Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite

Authors

CHYGORIN, Eduard (804 Ukraine, belonging to the institution), Lukáš PEČINKA (203 Czech Republic, belonging to the institution), Petr VAŇHARA (203 Czech Republic, belonging to the institution), Karel NOVOTNÝ (203 Czech Republic, belonging to the institution), Ivo KREMPL (203 Czech Republic, belonging to the institution) and Josef HAVEL (203 Czech Republic, guarantor, belonging to the institution)

Edition

Rapid Communications in Mass Spectrometry, Wiley, 2023, 0951-4198

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

20501 Materials engineering

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 2.000 in 2022

RIV identification code

RIV/00216224:14310/23:00131663

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1002/rcm.9520

UT WoS

000980740300001

Keywords in English

tellurides; mass spectrometry; synthesis; thin films

Abstract

V originále

Rationale: Carbides, including tellurium carbides (TeC), play crucial roles in diverse applications, but TeC synthesis has not been described in the literature. Laser ablation synthesis (LAS) coupled with mass spectrometry was used here for in situ TeC clusters synthesis and identification of the reaction products to better understand TeC formation. Methods: Laser desorption ionization time-of-flight mass spectrometry (LDI-TOFMS) was used to generate the TeC clusters and determine their stoichiometry via computer modeling of isotopic patterns. Results: A simple one-pot procedure was developed for Te-nanodiamond nanocomposite preparation. A suspension of fine-powdered Te was mixed with a suspension of nanodiamonds (both in acetonitrile), and the resulting precipitated nanocomposite was suitable for the synthesis of TemC(n) clusters using LDI. Various unary and binary clusters were formed. The stoichiometry of the novel TemC(n) clusters, determined via computer modeling of isotopic patterns, is reported here for the first time. Conclusions: The Te-nanodiamond composite was found to be the most suitable precursor for the generation of TemC(n) clusters. In total, 35 binary TemC(n) clusters were identified, when several of them were not obtained using commercial TeC material.

Links

GA22-07635S, research and development project

Name: Pokročilé metody přípravy telluridů polokovů a nepřechodných kovů

Investor: Czech Science Foundation

MUNI/A/1298/2022, interní kód MU

Name: Základní a aplikovaný výzkum a vývoj metod chemické a fyzikálně chemické analýzy pro studium přírody a pokročilé technologie

Investor: Masaryk University, Basic and applied research and development of chemical and physicochemical analytical methods for the study of nature and advanced technology

MUNI/A/1301/2022, interní kód MU

Name: Zdroje pro tkáňové inženýrství 13

Investor: Masaryk University

Citovat

CHYGORIN, Eduard, Lukáš PEČINKA, Petr VAŇHARA, Karel NOVOTNÝ, Ivo KREMPL and Josef HAVEL. Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite. Rapid Communications in Mass Spectrometry. Wiley, 2023, vol. 37, No 12, p. 1-6. ISSN 0951-4198. Available from: https://dx.doi.org/10.1002/rcm.9520.

@article{2309958,
   author = {Chygorin, Eduard and Pečinka, Lukáš and Vaňhara, Petr and Novotný, Karel and Krempl, Ivo and Havel, Josef},
   article_number = {12},
   doi = {http://dx.doi.org/10.1002/rcm.9520},
   keywords = {tellurides; mass spectrometry; synthesis; thin films},
   language = {eng},
   issn = {0951-4198},
   journal = {Rapid Communications in Mass Spectrometry},
   title = {Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite},
   url = {https://doi.org/10.1002/rcm.9520},
   volume = {37},
   year = {2023}
}

TY  - JOUR
ID  - 2309958
AU  - Chygorin, Eduard - Pečinka, Lukáš - Vaňhara, Petr - Novotný, Karel - Krempl, Ivo - Havel, Josef
PY  - 2023
TI  - Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite
JF  - Rapid Communications in Mass Spectrometry
VL  - 37
IS  - 12
SP  - 1-6
EP  - 1-6
PB  - Wiley
SN  - 09514198
KW  - tellurides
KW  - mass spectrometry
KW  - synthesis
KW  - thin films
UR  - https://doi.org/10.1002/rcm.9520
N2  - Rationale: Carbides, including tellurium carbides (TeC), play crucial roles in diverse applications, but TeC synthesis has not been described in the literature. Laser ablation synthesis (LAS) coupled with mass spectrometry was used here for in situ TeC clusters synthesis and identification of the reaction products to better understand TeC formation. Methods: Laser desorption ionization time-of-flight mass spectrometry (LDI-TOFMS) was used to generate the TeC clusters and determine their stoichiometry via computer modeling of isotopic patterns. Results: A simple one-pot procedure was developed for Te-nanodiamond nanocomposite preparation. A suspension of fine-powdered Te was mixed with a suspension of nanodiamonds (both in acetonitrile), and the resulting precipitated nanocomposite was suitable for the synthesis of TemC(n) clusters using LDI. Various unary and binary clusters were formed. The stoichiometry of the novel TemC(n) clusters, determined via computer modeling of isotopic patterns, is reported here for the first time. Conclusions: The Te-nanodiamond composite was found to be the most suitable precursor for the generation of TemC(n) clusters. In total, 35 binary TemC(n) clusters were identified, when several of them were not obtained using commercial TeC material.
ER  -

CHYGORIN, Eduard, Lukáš PEČINKA, Petr VAŇHARA, Karel NOVOTNÝ, Ivo KREMPL and Josef HAVEL. Laser ablation synthesis of tellurium carbides using tellurium with nanodiamond nanocomposite. \textit{Rapid Communications in Mass Spectrometry}. Wiley, 2023, vol.~37, No~12, p.~1-6. ISSN~0951-4198. Available from: https://dx.doi.org/10.1002/rcm.9520.

Detailed Information on Publication Record