Structurally diverse copper(II) phosphonates: Synthesis,
structure, and magnetism

J 2023

Structurally diverse copper(II) phosphonates: Synthesis, structure, and magnetism

DOROŠENKO, Jaroslav, Lucie ŠIMONÍKOVÁ, Zdeněk MORAVEC, Ján VANČO, Zdeněk TRÁVNÍČEK et. al.

Basic information

Original name

Structurally diverse copper(II) phosphonates: Synthesis, structure, and magnetism

Authors

DOROŠENKO, Jaroslav (203 Czech Republic, belonging to the institution), Lucie ŠIMONÍKOVÁ (203 Czech Republic, belonging to the institution), Zdeněk MORAVEC (203 Czech Republic, belonging to the institution), Ján VANČO, Zdeněk TRÁVNÍČEK and Jiří PINKAS (203 Czech Republic, guarantor, belonging to the institution)

Edition

POLYHEDRON, ENGLAND, PERGAMON-ELSEVIER SCIENCE LTD, 2023, 0277-5387

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 2.600 in 2022

RIV identification code

RIV/00216224:14310/23:00131948

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1016/j.poly.2023.116694

UT WoS

001102955500001

Keywords in English

Copper(II); Phosphonate; Synthesis; X-ray structures; Magnetism

Abstract

V originále

A dinuclear copper phosphonate [Cu2(AIPA)2(H2O)4] (1) (H2AIPA = (2-aminopropan-2-yl)phosphonic acid) was prepared, and its reaction with 4,4′-bipyridine (4,4′-bpy) and ethylenediamine (en) yielded a linear-chain polymeric complex having the composition {Cu2(AIPA)2(H2O)2(4,4′-bpy)}n (2), and an ionic complex [Cu (en)2(H2O)2][Cu(AIPA)2] (3), respectively. The complexes were thoroughly characterized, and their structures were determined by single-crystal X-ray diffraction. Complex 2 was formed by the substitution of the two coordinated water molecules in complex 1 with two 4,4′-bpy nitrogen atoms with the preservation of the cyclic dinuclear moiety and forming 1D-polymeric chains in which the {Cu2(AIPA)2} moieties are connected via the rigid 4,4′-bpy bridges. In contrast, the utilization of the chelating en ligands led to splitting the dinuclear core of 1 into the mononuclear [Cu(en)2(H2O)2]2+ cation and the [Cu(AIPA)2]2􀀀 anion forming the ionic complex (3). The temperature dependent (2.5–300 K) magnetic susceptibility at 0.1 T and field dependent magnetization measurement (in the range of 0–9 T at 2, 5, and 10 K) data are also presented and discussed, reflecting structural diversity of the complexes 1, 2, and 3, and showing the following best-fit parameters: J = –5.68(3) cm􀀀 1, gx = 1.900(1), gy = 2.098(5), gz = 2.399(1), zJ = –0.012(7) cm􀀀 1 (for 1), J1-2 = J3-4 = –0.24(4) cm􀀀 1 with giso = 2.319 (4), and J2-3 = 0.2(1) cm􀀀 1 with giso = 2.319(4), and with zJ = –0.021(2) cm􀀀 1 (for 2 modelled as a polymeric alternating chain consisting of bridged dimeric units) and J = 0.185(9) cm􀀀 1, gx = 2.12(2), gy = 2.13(3), gz = 2.13(3), and zJ = –0.01(1) cm􀀀 1 (for 3).

Links

EF18_046/0015974, research and development project

Name: Modernizace České infrastruktury pro integrativní strukturní biologii

EH22_008/0004572, research and development project

Name: Kvantové materiály pro aplikace v udržitelných technologiích

MUNI/A/1209/2022, interní kód MU

Name: Molekuly, komplexy, makrocykly a xerogely

Investor: Masaryk University, Molecules, complexes, macrocycles, and xerogels

MUNI/A/1575/2023, interní kód MU

Name: Metody chemické a fyzikálně-chemické analýzy pro studium přírodních a syntetických materiálů.

Investor: Masaryk University, Methods of chemical and physico-chemical analysis for the study of natural and synthetic materials.

90242, large research infrastructures

Name: CIISB III

Citovat

DOROŠENKO, Jaroslav, Lucie ŠIMONÍKOVÁ, Zdeněk MORAVEC, Ján VANČO, Zdeněk TRÁVNÍČEK and Jiří PINKAS. Structurally diverse copper(II) phosphonates: Synthesis, structure, and magnetism. POLYHEDRON. ENGLAND: PERGAMON-ELSEVIER SCIENCE LTD, 2023, vol. 246, DEC, p. 116694-116704. ISSN 0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2023.116694.

@article{2327080,
   author = {Dorošenko, Jaroslav and Šimoníková, Lucie and Moravec, Zdeněk and Vančo, Ján and Trávníček, Zdeněk and Pinkas, Jiří},
   article_location = {ENGLAND},
   article_number = {DEC},
   doi = {http://dx.doi.org/10.1016/j.poly.2023.116694},
   keywords = {Copper(II); Phosphonate; Synthesis; X-ray structures; Magnetism},
   language = {eng},
   issn = {0277-5387},
   journal = {POLYHEDRON},
   title = {Structurally diverse copper(II) phosphonates: Synthesis, structure, and magnetism},
   url = {https://www.sciencedirect.com/science/article/pii/S0277538723004163},
   volume = {246},
   year = {2023}
}

TY  - JOUR
ID  - 2327080
AU  - Dorošenko, Jaroslav - Šimoníková, Lucie - Moravec, Zdeněk - Vančo, Ján - Trávníček, Zdeněk - Pinkas, Jiří
PY  - 2023
TI  - Structurally diverse copper(II) phosphonates: Synthesis, structure, and magnetism
JF  - POLYHEDRON
VL  - 246
IS  - DEC
SP  - 116694
EP  - 116694
PB  - PERGAMON-ELSEVIER SCIENCE LTD
SN  - 02775387
KW  - Copper(II)
KW  - Phosphonate
KW  - Synthesis
KW  - X-ray structures
KW  - Magnetism
UR  - https://www.sciencedirect.com/science/article/pii/S0277538723004163
N2  - A dinuclear copper phosphonate [Cu2(AIPA)2(H2O)4] (1) (H2AIPA = (2-aminopropan-2-yl)phosphonic acid) was prepared, and its reaction with 4,4′-bipyridine (4,4′-bpy) and ethylenediamine (en) yielded a linear-chain polymeric complex having the composition {Cu2(AIPA)2(H2O)2(4,4′-bpy)}n (2), and an ionic complex [Cu (en)2(H2O)2][Cu(AIPA)2] (3), respectively. The complexes were thoroughly characterized, and their structures were determined by single-crystal X-ray diffraction. Complex 2 was formed by the substitution of the two coordinated water molecules in complex 1 with two 4,4′-bpy nitrogen atoms with the preservation of the cyclic dinuclear moiety and forming 1D-polymeric chains in which the {Cu2(AIPA)2} moieties are connected via the rigid 4,4′-bpy bridges. In contrast, the utilization of the chelating en ligands led to splitting the dinuclear core of 1 into the mononuclear [Cu(en)2(H2O)2]2+ cation and the [Cu(AIPA)2]2􀀀 anion forming the ionic complex (3). The temperature dependent (2.5–300 K) magnetic susceptibility at 0.1 T and field dependent magnetization measurement (in the range of 0–9 T at 2, 5, and 10 K) data are also presented and discussed, reflecting structural diversity of the complexes 1, 2, and 3, and showing the following best-fit parameters: J = –5.68(3) cm􀀀 1, gx = 1.900(1), gy = 2.098(5), gz = 2.399(1), zJ = –0.012(7) cm􀀀 1 (for 1), J1-2 = J3-4 = –0.24(4) cm􀀀 1 with giso = 2.319 (4), and J2-3 = 0.2(1) cm􀀀 1 with giso = 2.319(4), and with zJ = –0.021(2) cm􀀀 1 (for 2 modelled as a polymeric alternating chain consisting of bridged dimeric units) and J = 0.185(9) cm􀀀 1, gx = 2.12(2), gy = 2.13(3), gz = 2.13(3), and zJ = –0.01(1) cm􀀀 1 (for 3).
ER  -

DOROŠENKO, Jaroslav, Lucie ŠIMONÍKOVÁ, Zdeněk MORAVEC, Ján VANČO, Zdeněk TRÁVNÍČEK and Jiří PINKAS. Structurally diverse copper(II) phosphonates: Synthesis, structure, and magnetism. \textit{POLYHEDRON}. ENGLAND: PERGAMON-ELSEVIER SCIENCE LTD, 2023, vol.~246, DEC, p.~116694-116704. ISSN~0277-5387. Available from: https://dx.doi.org/10.1016/j.poly.2023.116694.

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