Ethanol Dehydrogenation over Copper-Silica Catalysts: From
Sub-Nanometer Clusters to 15 nm Large Particles

J 2023

Ethanol Dehydrogenation over Copper-Silica Catalysts: From Sub-Nanometer Clusters to 15 nm Large Particles

POKORNÝ, Tomáš, Vít VYKOUKAL, Petr MACHÁČ, Zdeněk MORAVEC, Nicola SCOTTI et. al.

Basic information

Original name

Ethanol Dehydrogenation over Copper-Silica Catalysts: From Sub-Nanometer Clusters to 15 nm Large Particles

Authors

POKORNÝ, Tomáš (203 Czech Republic, belonging to the institution), Vít VYKOUKAL (203 Czech Republic, belonging to the institution), Petr MACHÁČ (203 Czech Republic, belonging to the institution), Zdeněk MORAVEC (203 Czech Republic, belonging to the institution), Nicola SCOTTI, Pavla ROUPCOVA, Katerina KARASKOVA and Aleš STÝSKALÍK (203 Czech Republic, guarantor, belonging to the institution)

Edition

ACS Sustainable Chemistry and Engineering, American Chemical Society, 2023, 2168-0485

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

20402 Chemical process engineering

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 8.400 in 2022

RIV identification code

RIV/00216224:14310/23:00132141

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1021/acssuschemeng.2c06777

UT WoS

001033052800001

Keywords in English

ethanol dehydrogenation; copper; nanoparticles; acetaldehyde; sol-gel; dry impregnation

Abstract

V originále

Comparison of four preparation methodsshowed that the simpleand cost-effective dry impregnation provides Cu/SiO2 materialshowing the most stable catalytic behavior in potential renewableacetaldehyde production despite having a broad particle size distribution.

Links

EF18_046/0015974, research and development project

Name: Modernizace České infrastruktury pro integrativní strukturní biologii

GJ20-03636Y, research and development project

Name: Nové katalyzátory pro přípravu 1,3-butadienu z ethanolu

Investor: Czech Science Foundation

LM2018127, research and development project

Name: Česká infrastruktura pro integrativní strukturní biologii (Acronym: CIISB)

Investor: Ministry of Education, Youth and Sports of the CR

LM2023042, research and development project

Name: Česká infrastruktura pro integrativní strukturní biologii

Investor: Ministry of Education, Youth and Sports of the CR, CIISB - Czech Infrastructure for Integrative Structural Biology

MUNI/A/1209/2022, interní kód MU

Name: Molekuly, komplexy, makrocykly a xerogely

Investor: Masaryk University, Molecules, complexes, macrocycles, and xerogels

90110, large research infrastructures

Name: CzechNanoLab

Citovat

POKORNÝ, Tomáš, Vít VYKOUKAL, Petr MACHÁČ, Zdeněk MORAVEC, Nicola SCOTTI, Pavla ROUPCOVA, Katerina KARASKOVA and Aleš STÝSKALÍK. Ethanol Dehydrogenation over Copper-Silica Catalysts: From Sub-Nanometer Clusters to 15 nm Large Particles. ACS Sustainable Chemistry and Engineering. American Chemical Society, 2023, vol. 11, No 30, p. 10980-10992. ISSN 2168-0485. Available from: https://dx.doi.org/10.1021/acssuschemeng.2c06777.

@article{2334238,
   author = {Pokorný, Tomáš and Vykoukal, Vít and Macháč, Petr and Moravec, Zdeněk and Scotti, Nicola and Roupcova, Pavla and Karaskova, Katerina and Stýskalík, Aleš},
   article_number = {30},
   doi = {http://dx.doi.org/10.1021/acssuschemeng.2c06777},
   keywords = {ethanol dehydrogenation; copper; nanoparticles; acetaldehyde; sol-gel; dry impregnation},
   language = {eng},
   issn = {2168-0485},
   journal = {ACS Sustainable Chemistry and Engineering},
   title = {Ethanol Dehydrogenation over Copper-Silica Catalysts: From Sub-Nanometer Clusters to 15 nm Large Particles},
   url = {https://pubs.acs.org/doi/10.1021/acssuschemeng.2c06777},
   volume = {11},
   year = {2023}
}

TY  - JOUR
ID  - 2334238
AU  - Pokorný, Tomáš - Vykoukal, Vít - Macháč, Petr - Moravec, Zdeněk - Scotti, Nicola - Roupcova, Pavla - Karaskova, Katerina - Stýskalík, Aleš
PY  - 2023
TI  - Ethanol Dehydrogenation over Copper-Silica Catalysts: From Sub-Nanometer Clusters to 15 nm Large Particles
JF  - ACS Sustainable Chemistry and Engineering
VL  - 11
IS  - 30
SP  - 10980-10992
EP  - 10980-10992
PB  - American Chemical Society
SN  - 21680485
KW  - ethanol dehydrogenation
KW  - copper
KW  - nanoparticles
KW  - acetaldehyde
KW  - sol-gel
KW  - dry impregnation
UR  - https://pubs.acs.org/doi/10.1021/acssuschemeng.2c06777
N2  - Comparison of four preparation methodsshowed that the simpleand cost-effective dry impregnation provides Cu/SiO2 materialshowing the most stable catalytic behavior in potential renewableacetaldehyde production despite having a broad particle size distribution.
ER  -

POKORNÝ, Tomáš, Vít VYKOUKAL, Petr MACHÁČ, Zdeněk MORAVEC, Nicola SCOTTI, Pavla ROUPCOVA, Katerina KARASKOVA and Aleš STÝSKALÍK. Ethanol Dehydrogenation over Copper-Silica Catalysts: From Sub-Nanometer Clusters to 15 nm Large Particles. \textit{ACS Sustainable Chemistry and Engineering}. American Chemical Society, 2023, vol.~11, No~30, p.~10980-10992. ISSN~2168-0485. Available from: https://dx.doi.org/10.1021/acssuschemeng.2c06777.

Detailed Information on Publication Record