Detailed Information on Publication Record
2023
"Activated Borane": A Porous Borane Cluster Polymer as an Efficient Lewis Acid-Based Catalyst
LAMAC, Martin, Bela URBAN, Michal HORACEK, Daniel BUZEK, Lucie LEONOVÁ et. al.Basic information
Original name
"Activated Borane": A Porous Borane Cluster Polymer as an Efficient Lewis Acid-Based Catalyst
Authors
LAMAC, Martin, Bela URBAN, Michal HORACEK, Daniel BUZEK, Lucie LEONOVÁ (203 Czech Republic, belonging to the institution), Aleš STÝSKALÍK (203 Czech Republic, guarantor, belonging to the institution), Anna VYKYDALOVA, Karel SKOCH, Matous KLODA, Andrii MAHUN, Libor KOBERA, Kamil LANG, Michael G S LONDESBOROUGH and Jan DEMEL
Edition
ACS Catalysis, WASHINGTON, AMER CHEMICAL SOC, 2023, 2155-5435
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
United States of America
Confidentiality degree
není předmětem státního či obchodního tajemství
References:
Impact factor
Impact factor: 12.900 in 2022
RIV identification code
RIV/00216224:14310/23:00133080
Organization unit
Faculty of Science
UT WoS
001122449600001
Keywords in English
activated borane; Lewis acid catalyst; heterogeneouscatalysis; deoxygenation reaction; ethanol dehydration; Gutmann-Beckett method; solid-state NMR
Tags
Tags
International impact, Reviewed
Změněno: 8/4/2024 14:39, Mgr. Marie Šípková, DiS.
Abstract
V originále
Borane cluster-based porous covalent networks, named activated borane (ActB), were prepared by cothermolysis of decaborane(14) (nido-B10H14) and selected hydrocarbons (toluene, ActB-Tol; cyclohexane, ActB-cyHx; and n-hexane, ActB-nHx) under anaerobic conditions. These amorphous solid powders exhibit different textural and Lewis acid (LA) properties that vary depending on the nature of the constituent organic linker. For ActB-Tol, its LA strength even approaches that of the commonly used molecular LA, B(C6F5)(3). Most notably, ActBs can act as heterogeneous LA catalysts in hydrosilylation/deoxygenation reactions with various carbonyl substrates as well as in the gas-phase dehydration of ethanol. These studies reveal the potential of ActBs in catalytic applications, showing (a) the possibility for tuning catalytic reaction outcomes (selectivity) in hydrosilylation/deoxygenation reactions by changing the material's composition and (b) the very high activity toward ethanol dehydration that exceeds the commonly used gamma-Al2O3 by achieving a stable conversion of similar to 93% with a selectivity for ethylene production of similar to 78% during a 17 h continuous period on stream at 240 degrees C.
Links
| MUNI/A/1209/2022, interní kód MU |
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| MUNI/J/0007/2021, interní kód MU |
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