J 2024

Fluid Evolution of Greisens from Krupka Sn-W Ore District, Bohemian Massif (Czech Republic)

KREJČÍ KOTLÁNOVÁ, Michaela, Zdeněk DOLNÍČEK, Miloš RENÉ, Walter PROCHASKA, Jana ULMANOVÁ et. al.

Basic information

Original name

Fluid Evolution of Greisens from Krupka Sn-W Ore District, Bohemian Massif (Czech Republic)

Authors

KREJČÍ KOTLÁNOVÁ, Michaela (203 Czech Republic, belonging to the institution), Zdeněk DOLNÍČEK (203 Czech Republic), Miloš RENÉ, Walter PROCHASKA, Jana ULMANOVÁ, Jaroslav KAPUSTA, Vlastimil MAŠEK and Kamil KROPÁČ

Edition

Minerals, MDPI, 2024, 2075-163X

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10504 Mineralogy

Country of publisher

Switzerland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

Impact factor

Impact factor: 2.500 in 2022

Organization unit

Faculty of Science

UT WoS

001152423300001

Keywords in English

Krupka; Bohemian Massif; greisen; Sn-W mineralization; fluid inclusions; stable isotopes of hydrogen; crush-leach analyses; Raman spectroscopy

Tags

Tags

International impact, Reviewed
Změněno: 11/4/2024 11:05, Mgr. Marie Šípková, DiS.

Abstract

V originále

The Sn-W ore deposits in the Krupka surroundings are associated with greisens, which occur in the upper parts of Late Variscan granitoid intrusions. Fluid inclusions were studied in samples of quartz, cassiterite, apatite, fluorite, and topaz in greisenized granites, greisens, and hydrothermal veins with Sn-W mineralization. The greisenization process took place at temperatures 370–490 °C and pressures 155–371 bars, and associated fluids had predominantly low salinity and a low gas (CO2, N2 and CH4) content. The post-greisenization stage was connected with the formation of (i) low-salinity (0–8 wt. % NaCl eq.) fluid inclusions with homogenization temperatures <120–295 °C and (ii) high-salinity (18 to >35 wt. % NaCl eq.) fluid inclusions with homogenization temperatures 140–370 °C, often containing trapped crystals of quartz, topaz, and sulfides, or daughter crystals of salts and carbonates, which were identified by microthermometric measurements, electron microprobe analysis, and Raman spectroscopy. Analyses of fluid inclusion leachates have shown that Na and Ca chlorides predominate in fluids. According to hydrogen stable isotopes, the source of greisenizing and post-greisenizing fluids was not only magmatogenic but also meteoric water or fluids derived from sedimentary rocks.