Metal-organic framework composites for electrochemical CO2
reduction reaction

J 2024

Metal-organic framework composites for electrochemical CO2 reduction reaction

ADEGOKE, Kayode A., Joshua O. IGHALO, Jeanet CONRADIE, Chinemerem R. OHORO, James F. AMAKU et. al.

Basic information

Original name

Metal-organic framework composites for electrochemical CO2 reduction reaction

Authors

Edition

Separation and Purification Technology, Elsevier B.V. 2024, 1383-5866

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

20400 2.4 Chemical engineering

Country of publisher

Netherlands

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 8.600 in 2022

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1016/j.seppur.2024.126532

UT WoS

001210981100001

Keywords in English

Anthropogenic activities; CO2 reduction reaction; Electrocatalyst; Metal-organic framework composites; Environmental sustainability

Abstract

V originále

Carbon dioxide (CO2) levels in the atmosphere are quickly increasing as a consequence of anthropogenic activities, which present grave hazards and dangerous circumstances to not only humanity but also the ecosystem. Currently, electrochemical CO2 conversion to chemical/fuels remains one of the best methods for minimizing CO2 concentrations. Metal-organic frameworks (MOFs) composite materials have been considered as new class of highly-performed electrocatalysts for CO2 reduction reaction (CO2RR) due to their wide surface area, higher porosity, chemical tunability and excellent stability. This article presents major approaches for electrochemical CO2RR to value-added product. These were followed by discussing the recent advancements in MOF composite electrocatalysts for CO2RR including active sites MOF-supported electrocatalysts, metal-nanoparticlessupported MOFs, conductive supported MOFs composites, and polyoxometalate-based MOF composites. Lastly, some challenges currently facing MOF composites for CO2RR as well as anticipated future advances were discussed. Research hotspot lies in the creation of highly effective CO2RR electrocatalyst such as ligand engineering in MOFs. It is believed that the current study will contribute to accelerating the fabrication of efficient MOF composite materials for abating the CO2 emission in the ecosystem and to highlight the necessity for further research to address significant environmental sustainability concerns.

Citovat

ADEGOKE, Kayode A., Joshua O. IGHALO, Jeanet CONRADIE, Chinemerem R. OHORO, James F. AMAKU, Kabir O. OYEDOTUN, Nobanathi W. MAXAKATO, Kovo G. AKPOMIE, Emmanuel Sunday OKEKE, Chijioke OLISAH and Alhadji MALLOUM. Metal-organic framework composites for electrochemical CO2 reduction reaction. Separation and Purification Technology. Elsevier B.V., 2024, vol. 341, August 2024, p. 1-23. ISSN 1383-5866. Available from: https://dx.doi.org/10.1016/j.seppur.2024.126532.

@article{2407857,
   author = {Adegoke, Kayode A. and Ighalo, Joshua O. and Conradie, Jeanet and Ohoro, Chinemerem R. and Amaku, James F. and Oyedotun, Kabir O. and Maxakato, Nobanathi W. and Akpomie, Kovo G. and Okeke, Emmanuel Sunday and Olisah, Chijioke and Malloum, Alhadji},
   article_number = {August 2024},
   doi = {http://dx.doi.org/10.1016/j.seppur.2024.126532},
   keywords = {Anthropogenic activities; CO2 reduction reaction; Electrocatalyst; Metal-organic framework composites; Environmental sustainability},
   language = {eng},
   issn = {1383-5866},
   journal = {Separation and Purification Technology},
   title = {Metal-organic framework composites for electrochemical CO2 reduction reaction},
   url = {https://www.sciencedirect.com/science/article/abs/pii/S1383586624002715?via%3Dihub},
   volume = {341},
   year = {2024}
}

TY  - JOUR
ID  - 2407857
AU  - Adegoke, Kayode A. - Ighalo, Joshua O. - Conradie, Jeanet - Ohoro, Chinemerem R. - Amaku, James F. - Oyedotun, Kabir O. - Maxakato, Nobanathi W. - Akpomie, Kovo G. - Okeke, Emmanuel Sunday - Olisah, Chijioke - Malloum, Alhadji
PY  - 2024
TI  - Metal-organic framework composites for electrochemical CO2 reduction reaction
JF  - Separation and Purification Technology
VL  - 341
IS  - August 2024
SP  - 1-23
EP  - 1-23
PB  - Elsevier B.V.
SN  - 13835866
KW  - Anthropogenic activities
KW  - CO2 reduction reaction
KW  - Electrocatalyst
KW  - Metal-organic framework composites
KW  - Environmental sustainability
UR  - https://www.sciencedirect.com/science/article/abs/pii/S1383586624002715?via%3Dihub
N2  - Carbon dioxide (CO2) levels in the atmosphere are quickly increasing as a consequence of anthropogenic activities, which present grave hazards and dangerous circumstances to not only humanity but also the ecosystem. Currently, electrochemical CO2 conversion to chemical/fuels remains one of the best methods for minimizing CO2 concentrations. Metal-organic frameworks (MOFs) composite materials have been considered as new class of highly-performed electrocatalysts for CO2 reduction reaction (CO2RR) due to their wide surface area, higher porosity, chemical tunability and excellent stability. This article presents major approaches for electrochemical CO2RR to value-added product. These were followed by discussing the recent advancements in MOF composite electrocatalysts for CO2RR including active sites MOF-supported electrocatalysts, metal-nanoparticlessupported MOFs, conductive supported MOFs composites, and polyoxometalate-based MOF composites. Lastly, some challenges currently facing MOF composites for CO2RR as well as anticipated future advances were discussed. Research hotspot lies in the creation of highly effective CO2RR electrocatalyst such as ligand engineering in MOFs. It is believed that the current study will contribute to accelerating the fabrication of efficient MOF composite materials for abating the CO2 emission in the ecosystem and to highlight the necessity for further research to address significant environmental sustainability concerns.
ER  -

ADEGOKE, Kayode A., Joshua O. IGHALO, Jeanet CONRADIE, Chinemerem R. OHORO, James F. AMAKU, Kabir O. OYEDOTUN, Nobanathi W. MAXAKATO, Kovo G. AKPOMIE, Emmanuel Sunday OKEKE, Chijioke OLISAH and Alhadji MALLOUM. Metal-organic framework composites for electrochemical CO2 reduction reaction. \textit{Separation and Purification Technology}. Elsevier B.V., 2024, vol.~341, August 2024, p.~1-23. ISSN~1383-5866. Available from: https://dx.doi.org/10.1016/j.seppur.2024.126532.

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