Achievements and Challenges with Equilibrium and Kinetic
Passive Sampling of Hydrophobic and Hydrophilic Organic
Compounds in Surface Waters

J 2025

Achievements and Challenges with Equilibrium and Kinetic Passive Sampling of Hydrophobic and Hydrophilic Organic Compounds in Surface Waters

BOOIJ, Kees; Rachel MACKIE; Branislav VRANA; Rainer LOHMANN; Sarit L. KASERZON et. al.

Základní údaje

Originální název

Achievements and Challenges with Equilibrium and Kinetic Passive Sampling of Hydrophobic and Hydrophilic Organic Compounds in Surface Waters

Autoři

BOOIJ, Kees; Rachel MACKIE; Branislav VRANA ; Rainer LOHMANN a Sarit L. KASERZON

Vydání

ACS ES&T WATER, WASHINGTON, AMER CHEMICAL SOC, 2025, 2690-0637

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10503 Water resources

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.300 v roce 2024

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.1021/acsestwater.5c00384

UT WoS

001535132400001

EID Scopus

2-s2.0-105014650678

Klíčová slova anglicky

SEMIPERMEABLE-MEMBRANE DEVICES; PERSONAL CARE PRODUCTS; IN-SITU CALIBRATION; DIFFUSIVE GRADIENTS; POLAR; SAMPLERS; CONTAMINANTS; CHEMICALS; POCIS; RATES

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 19. 9. 2025 12:09, Mgr. Michaela Hylsová, Ph.D.

Anotace

V originále

Passive sampling in surface waters is an important method in the monitoring and risk assessment of hydrophobic and hydrophilic organic chemicals. Sampler designs can be optimized for fast equilibrium attainment (equilibrium sampling) or improved time-integrative capability (kinetic sampling). We argue that both equilibrium and kinetic sampling can be applied when aqueous concentrations do not vary with time, whereas kinetic sampling also yields useful results for time-variable concentrations that are often observed with hydrophilic compounds in surface waters. We show that these methods have similar accuracy in principle but that their dominant error sources are different: sampler-water sorption coefficients for equilibrium sampling and sampling rates for kinetic sampling. In contrast to passive sampling of hydrophobic compounds, passive sampling of hydrophilic compounds is not as well-established, but major progress has been made over the past decade in the modeling of transport through the water boundary layer, membrane, and sorbent, while less progress has been made for transport in the biofouling layer. We recommend a more extensive use of diffusion cells as a research tool to gain a better understanding of transport through the respective subphases, leading to a greater maturity of passive water sampling of hydrophilic compounds.

Návaznosti

GX20-04676X, projekt VaV

Název: Holistická charakterizace expozice a potenciálních účinků komplexních směsí chemických látek ve vodním prostředí

Investor: Grantová agentura ČR, Holistická charakterizace expozice a potenciálních účinků komplexních směsí chemických látek ve vodním prostředí

LM2023069, projekt VaV

Název: Výzkumná infrastruktura RECETOX

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Výzkumná infrastruktura RECETOX

Citovat

BOOIJ, Kees; Rachel MACKIE; Branislav VRANA; Rainer LOHMANN a Sarit L. KASERZON. Achievements and Challenges with Equilibrium and Kinetic Passive Sampling of Hydrophobic and Hydrophilic Organic Compounds in Surface Waters. ACS ES&T WATER. WASHINGTON: AMER CHEMICAL SOC, 2025, roč. 5, č. 8, s. 4343-4350. ISSN 2690-0637. Dostupné z: https://doi.org/10.1021/acsestwater.5c00384.

@article{2519783,
   author = {Booij, Kees and Mackie, Rachel and Vrana, Branislav and Lohmann, Rainer and Kaserzon, Sarit L.},
   article_location = {WASHINGTON},
   article_number = {8},
   doi = {https://doi.org/10.1021/acsestwater.5c00384},
   keywords = {SEMIPERMEABLE-MEMBRANE DEVICES; PERSONAL CARE PRODUCTS; IN-SITU CALIBRATION; DIFFUSIVE GRADIENTS; POLAR; SAMPLERS; CONTAMINANTS; CHEMICALS; POCIS; RATES},
   language = {eng},
   issn = {2690-0637},
   journal = {ACS ES&T WATER},
   title = {Achievements and Challenges with Equilibrium and Kinetic Passive Sampling of Hydrophobic and Hydrophilic Organic Compounds in Surface Waters},
   url = {https://pubs.acs.org/doi/10.1021/acsestwater.5c00384},
   volume = {5},
   year = {2025}
}

TY  - JOUR
ID  - 2519783
AU  - Booij, Kees - Mackie, Rachel - Vrana, Branislav - Lohmann, Rainer - Kaserzon, Sarit L.
PY  - 2025
TI  - Achievements and Challenges with Equilibrium and Kinetic Passive Sampling of Hydrophobic and Hydrophilic Organic Compounds in Surface Waters
JF  - ACS ES&T WATER
VL  - 5
IS  - 8
SP  - 4343-4350
EP  - 4343-4350
PB  - AMER CHEMICAL SOC
SN  - 26900637
KW  - SEMIPERMEABLE-MEMBRANE DEVICES
KW  - PERSONAL CARE PRODUCTS
KW  - IN-SITU CALIBRATION
KW  - DIFFUSIVE GRADIENTS
KW  - POLAR
KW  - SAMPLERS
KW  - CONTAMINANTS
KW  - CHEMICALS
KW  - POCIS
KW  - RATES
UR  - https://pubs.acs.org/doi/10.1021/acsestwater.5c00384
N2  - Passive sampling in surface waters is an important method in the monitoring and risk assessment of hydrophobic and hydrophilic organic chemicals. Sampler designs can be optimized for fast equilibrium attainment (equilibrium sampling) or improved time-integrative capability (kinetic sampling). We argue that both equilibrium and kinetic sampling can be applied when aqueous concentrations do not vary with time, whereas kinetic sampling also yields useful results for time-variable concentrations that are often observed with hydrophilic compounds in surface waters. We show that these methods have similar accuracy in principle but that their dominant error sources are different: sampler-water sorption coefficients for equilibrium sampling and sampling rates for kinetic sampling. In contrast to passive sampling of hydrophobic compounds, passive sampling of hydrophilic compounds is not as well-established, but major progress has been made over the past decade in the modeling of transport through the water boundary layer, membrane, and sorbent, while less progress has been made for transport in the biofouling layer. We recommend a more extensive use of diffusion cells as a research tool to gain a better understanding of transport through the respective subphases, leading to a greater maturity of passive water sampling of hydrophilic compounds.
ER  -

BOOIJ, Kees; Rachel MACKIE; Branislav VRANA; Rainer LOHMANN a Sarit L. KASERZON. Achievements and Challenges with Equilibrium and Kinetic Passive Sampling of Hydrophobic and Hydrophilic Organic Compounds in Surface Waters. \textit{ACS ES\&{}amp;T WATER}. WASHINGTON: AMER CHEMICAL SOC, 2025, roč.~5, č.~8, s.~4343-4350. ISSN~2690-0637. Dostupné z: https://doi.org/10.1021/acsestwater.5c00384.

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