Supramolecular confinement as a tool to control the dynamic
molecular assembly of o-nitrosocumene in water

J 2025

Supramolecular confinement as a tool to control the dynamic molecular assembly of o-nitrosocumene in water

PRADEEP, Anu; Cory H. ROGERS; Ramkumar VARADHARAJAN; S. Ariel KELLEY; Radek MAREK et. al.

Základní údaje

Originální název

Supramolecular confinement as a tool to control the dynamic molecular assembly of o-nitrosocumene in water

Autoři

PRADEEP, Anu; Cory H. ROGERS; Ramkumar VARADHARAJAN; S. Ariel KELLEY; Radek MAREK ; Silas C. BLACKSTOCK a Vaidhyanathan RAMAMURTHY

Vydání

CHEMICAL COMMUNICATIONS, Royal Society of Chemistry, 2025, 1359-7345

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10400 1.4 Chemical sciences

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

DOI: 10.1039/D5CC04999G

Impakt faktor

Impact factor: 4.200 v roce 2024

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.1039/D5CC04999G

Klíčová slova anglicky

molecular assembly; supramolecular; NMR spectroscopy; cavitand; capsule

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 12. 11. 2025 07:57, prof. RNDr. Radek Marek, Ph.D.

Anotace

V originále

The results presented here collectively illustrate that in addition to temperature and concentration, macrocyclic hosts cucurbiturils, cyclodextrins, and octa acid can be employed to manipulate the complex equilibria of ortho-nitrosocumene monomers (M), dimers (D), and their non-covalent aggregates (A) in water. The extent and location of free space and the micropolarity of the reaction cavity are important in controlling the dynamics of the guests confined in the octa acid capsule to fully tilt the M–D equilibrium towards M, even when two M are packed in a single capsule.

Návaznosti

GA24-10760S, projekt VaV

Název: Relativistické spin-orbitální efekty v molekulární struktuře a NMR spektroskopii

Investor: Grantová agentura ČR, Relativistické spin-orbitální efekty v molekulární struktuře a NMR spektroskopii

Citovat

PRADEEP, Anu; Cory H. ROGERS; Ramkumar VARADHARAJAN; S. Ariel KELLEY; Radek MAREK; Silas C. BLACKSTOCK a Vaidhyanathan RAMAMURTHY. Supramolecular confinement as a tool to control the dynamic molecular assembly of o-nitrosocumene in water. CHEMICAL COMMUNICATIONS. Royal Society of Chemistry, 2025, č. 95, s. 10000-10003. ISSN 1359-7345. Dostupné z: https://doi.org/10.1039/D5CC04999G.

@article{2532477,
   author = {Pradeep, Anu and Rogers, Cory H. and Varadharajan, Ramkumar and Kelley, S. Ariel and Marek, Radek and Blackstock, Silas C. and Ramamurthy, Vaidhyanathan},
   article_number = {95},
   doi = {https://doi.org/10.1039/D5CC04999G},
   keywords = {molecular assembly; supramolecular; NMR spectroscopy; cavitand; capsule},
   language = {eng},
   issn = {1359-7345},
   journal = {CHEMICAL COMMUNICATIONS},
   title = {Supramolecular confinement as a tool to control the dynamic molecular assembly of o-nitrosocumene in water},
   url = {https://doi.org/10.1039/D5CC04999G},
   year = {2025}
}

TY  - JOUR
ID  - 2532477
AU  - Pradeep, Anu - Rogers, Cory H. - Varadharajan, Ramkumar - Kelley, S. Ariel - Marek, Radek - Blackstock, Silas C. - Ramamurthy, Vaidhyanathan
PY  - 2025
TI  - Supramolecular confinement as a tool to control the dynamic molecular assembly of o-nitrosocumene in water
JF  - CHEMICAL COMMUNICATIONS
IS  - 95
SP  - 10000-10003
EP  - 10000-10003
PB  - Royal Society of Chemistry
SN  - 13597345
KW  - molecular assembly
KW  - supramolecular
KW  - NMR spectroscopy
KW  - cavitand
KW  - capsule
UR  - https://doi.org/10.1039/D5CC04999G
N2  - The results presented here collectively illustrate that in addition to temperature and concentration, macrocyclic hosts cucurbiturils, cyclodextrins, and octa acid can be employed to manipulate the complex equilibria of ortho-nitrosocumene monomers (M), dimers (D), and their non-covalent aggregates (A) in water. The extent and location of free space and the micropolarity of the reaction cavity are important in controlling the dynamics of the guests confined in the octa acid capsule to fully tilt the M–D equilibrium towards M, even when two M are packed in a single capsule.
ER  -

PRADEEP, Anu; Cory H. ROGERS; Ramkumar VARADHARAJAN; S. Ariel KELLEY; Radek MAREK; Silas C. BLACKSTOCK a Vaidhyanathan RAMAMURTHY. Supramolecular confinement as a tool to control the dynamic molecular assembly of o-nitrosocumene in water. \textit{CHEMICAL COMMUNICATIONS}. Royal Society of Chemistry, 2025, č.~95, s.~10000-10003. ISSN~1359-7345. Dostupné z: https://doi.org/10.1039/D5CC04999G.

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