J 1998

Adsorption and condensation of xanthine at the mercury/solution interface.

DRAŽAN, Viktor and Vladimír VETTERL

Basic information

Original name

Adsorption and condensation of xanthine at the mercury/solution interface.

Authors

DRAŽAN, Viktor and Vladimír VETTERL (203 Czech Republic, guarantor)

Edition

Collections of Czechoslovac Chemical Communications, Praha, 1998, 0010-0765

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10610 Biophysics

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 0.546

RIV identification code

RIV/00216224:14330/98:00004088

Organization unit

Faculty of Informatics

Keywords in English

Frumkin adsorption isotherm; xanthine; electrochemical impedance; differential capacitance; Ising model;
Změněno: 29/5/2003 11:11, prof. RNDr. Vladimír Vetterl, DrSc.

Abstract

V originále

The adsorption and two-dimensional condensation of xanthine at the mercury electrode in 0.2 M and 2 M NaCl was studied by electrode double layer impedance measurements. The two-dimensional condesation of xanthine was observed at pH 6.0 and pH 7.4 but not at pH 9.0. The standard Gibbs energy of adsorption, energy of lateral interactions and the suurface occupied by one xanthine molecule in the compact layer were calculated from the temperature dependence of the capacitance pit width using Frumkin and Ising (lattice gas) models.

Links

GV204/97/K084, research and development project
Name: Elektrody modifikované nukleovými kyselinami a bílkovinami. Nové nástroje v biochemickém a biomedicínském výzkumu
Investor: Czech Science Foundation, Electrodes modified with nucleic acids and proteins. New tools in biochemical and biomedical research
IAA4004702, research and development project
Name: Adsorpce bazí, nukleosidů, nukleotidů a polynukleotidů na elektrodách
Investor: Academy of Sciences of the Czech Republic, Adsorption of bases, nucleosides, nucleotides and polynucleotides on electrods