Synthesis and Structural Characterization of Functionalized
Dimeric Aluminophosphonates and a Monomeric Gallophosphonate
Anion

J 2001

Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion

CHAKRABORTY, Debashis, Sabine HORCHLER, Ralph KRÄTZNER, Saji P. VARKEY, Jiří PINKAS et. al.

Basic information

Original name

Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion

Authors

CHAKRABORTY, Debashis, Sabine HORCHLER, Ralph KRÄTZNER, Saji P. VARKEY, Jiří PINKAS, Herbert W. ROESKY, Isabel USÓN, Mathias NOLTEMEYER and Hans-Georg SCHMIDT

Edition

Inorg. Chem. Spojené státy americké, American Chemical Society, Washington DC, 2001, 0020-1669

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 2.946

RIV identification code

RIV/00216224:14310/01:00004222

Organization unit

Faculty of Science

Keywords in English

CRYSTAL-STRUCTURE; MOLECULAR-SIEVES; MODEL-COMPOUND; ZEOLITE-Y; GALLIUM; CATALYST;

Abstract

V originále

Reaction of t-BuP(O)(OSiMe3)(OH) with Me3Al leads to the formation of [Me2Al(mu -O)(2)P(OSiMe3)(t-Bu)](2) (1) whereas Me2AlCl reacts with Ph2P(O)(OH) to yield [(Cl)(Me)Al(mu -O)(2)PPh2](2) (2). These compounds represent the first examples of functionalized dimeric four-ring type aluminophosphonate systems. The double four-ring type gallophosphonate, namely, [t-BuPO3GaMe](4), reacts with n-Bu4NHF2 under ambient conditions, resulting in the formation of a monomeric gallophosphonate [n-Bu4N][MeGa(t-BuPO2(OH))(3)] (3) These derivatives have been adequately characterized using various spectroscopic techniques and X-ray diffraction studies.

Links

GA203/01/1533, research and development project

Name: Nové bezvodé metody přípravy fosfátových, silikátových, hybridních a oxidických materiálů

Investor: Czech Science Foundation, New Nonaqueous Routes to Phosphate, Silicate, Hybrid, and Oxide Materials

Citovat

CHAKRABORTY, Debashis, Sabine HORCHLER, Ralph KRÄTZNER, Saji P. VARKEY, Jiří PINKAS, Herbert W. ROESKY, Isabel USÓN, Mathias NOLTEMEYER and Hans-Georg SCHMIDT. Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion. Inorg. Chem. Spojené státy americké: American Chemical Society, Washington DC, 2001, vol. 40, No 11, p. 2620-2624. ISSN 0020-1669.

@article{362632,
   author = {Chakraborty, Debashis and Horchler, Sabine and Krätzner, Ralph and Varkey, Saji P. and Pinkas, Jiří and Roesky, Herbert W. and Usón, Isabel and Noltemeyer, Mathias and Schmidt, HansandGeorg},
   article_location = {Spojené státy americké},
   article_number = {11},
   keywords = {CRYSTAL-STRUCTURE; MOLECULAR-SIEVES; MODEL-COMPOUND; ZEOLITE-Y; GALLIUM; CATALYST;},
   language = {eng},
   issn = {0020-1669},
   journal = {Inorg. Chem.},
   title = {Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion},
   volume = {40},
   year = {2001}
}

TY  - JOUR
ID  - 362632
AU  - Chakraborty, Debashis - Horchler, Sabine - Krätzner, Ralph - Varkey, Saji P. - Pinkas, Jiří - Roesky, Herbert W. - Usón, Isabel - Noltemeyer, Mathias - Schmidt, Hans-Georg
PY  - 2001
TI  - Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion
JF  - Inorg. Chem.
VL  - 40
IS  - 11
SP  - 2620
EP  - 2620
PB  - American Chemical Society, Washington DC
SN  - 00201669
KW  - CRYSTAL-STRUCTURE
KW  - MOLECULAR-SIEVES
KW  - MODEL-COMPOUND
KW  - ZEOLITE-Y
KW  - GALLIUM
KW  - CATALYST;
N2  - Reaction of t-BuP(O)(OSiMe3)(OH) with Me3Al leads to the formation of [Me2Al(mu -O)(2)P(OSiMe3)(t-Bu)](2) (1) whereas Me2AlCl reacts with Ph2P(O)(OH) to yield [(Cl)(Me)Al(mu -O)(2)PPh2](2) (2). These compounds represent the first examples of functionalized dimeric four-ring type aluminophosphonate systems. The double four-ring type gallophosphonate, namely, [t-BuPO3GaMe](4), reacts with n-Bu4NHF2 under ambient conditions, resulting in the formation of a monomeric gallophosphonate [n-Bu4N][MeGa(t-BuPO2(OH))(3)] (3) These derivatives have been adequately characterized using various spectroscopic techniques and X-ray diffraction studies.
ER  -

CHAKRABORTY, Debashis, Sabine HORCHLER, Ralph KRÄTZNER, Saji P. VARKEY, Jiří PINKAS, Herbert W. ROESKY, Isabel USÓN, Mathias NOLTEMEYER and Hans-Georg SCHMIDT. Synthesis and Structural Characterization of Functionalized Dimeric Aluminophosphonates and a Monomeric Gallophosphonate Anion. \textit{Inorg. Chem.}. Spojené státy americké: American Chemical Society, Washington DC, 2001, vol.~40, No~11, p.~2620-2624. ISSN~0020-1669.

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