Detailed Information on Publication Record
2001
Diastereoselectivity in 1,3-dipolar cycloaddition reactions of alpha-methylene lactone derivatives
ČASTULÍK, Jakub, Petr MELŠA and Ctibor MAZALBasic information
Original name
Diastereoselectivity in 1,3-dipolar cycloaddition reactions of alpha-methylene lactone derivatives
Authors
ČASTULÍK, Jakub (203 Czech Republic), Petr MELŠA (203 Czech Republic) and Ctibor MAZAL (203 Czech Republic, guarantor)
Edition
Prague, 9th Meeting on Stereochemistry, Book of Abstracts, p. 161-162, 2001
Publisher
Institute of Chemical Technology, Prague and Czech Chemical Society
Other information
Language
English
Type of outcome
Stať ve sborníku
Field of Study
10401 Organic chemistry
Country of publisher
Czech Republic
Confidentiality degree
není předmětem státního či obchodního tajemství
RIV identification code
RIV/00216224:14310/01:00006003
Organization unit
Faculty of Science
ISBN
80-7080-427-0
Keywords in English
Stereoselectivity; Methylene Lactones; 1;3-Dipolar Cycloaddition
Změněno: 20/5/2003 16:12, doc. RNDr. Ctibor Mazal, CSc.
Abstract
V originále
Alpha-methylene lactones added stereoselectively various kinds of 1,3-dipolar compounds. Spiro pyrrolidines and spiro pyrrolizidines were prepared by addition of azomethin ylides generated from sarcosin and prolin resp. Cycloaddition of a photochemically generated nitril ylide showed an unusual exo-selectivity. Alpha-methylene-gamma-lactone with a bulky substituent (OBO) in gamma position, which was prepared as a single enantiomer from L-glutamic acid, added 1,3-dipolar compounds in anti-manner almost exclusively.
Links
| MSM 143100011, plan (intention) |
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