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@article{365951,
author = {Klán, Petr and Del Favero, David and Ansorgová, Alena and Klánová, Jana and Holoubek, Ivan},
article_location = {Landsberg, Germany},
article_number = {3},
keywords = {phototransformation; snow; ice; POPs},
language = {eng},
issn = {0944-1344},
journal = {Environmental Science and Pollution Research},
title = {Photodegradation of Halobenzenes in Water Ice},
url = {http://www.scientificjournals.com/ESPR/},
volume = {8},
year = {2001}
}
TY - JOUR
ID - 365951
AU - Klán, Petr - Del Favero, David - Ansorgová, Alena - Klánová, Jana - Holoubek, Ivan
PY - 2001
TI - Photodegradation of Halobenzenes in Water Ice
JF - Environmental Science and Pollution Research
VL - 8
IS - 3
SP - 195
EP - 195
PB - Ecomed
SN - 09441344
KW - phototransformation
KW - snow
KW - ice
KW - POPs
UR - http://www.scientificjournals.com/ESPR/
N2 - Results from the photolysis of o-, p-dichlorobenzene, bromobenzene, and p-dibromobenzene in water ice are reported. All phototransformations appeared to be based on dehalogenation, coupling, and rearrangement reactions in ice cavities. No photosolvolysis products, i.e. products from intermolecular reactions between organic and water molecules, were found. Many of the products were very toxic substances of a high environmental risk, such as PCBs. The results support our model, in which secondary, very toxic, pollutants can be formed in ice, snow, and atmospheric ice particles from primary pollutants by solar irradiation. The photoproducts may be released to the environment by ice melting and evaporation.
ER -
KLÁN, Petr, David DEL FAVERO, Alena ANSORGOVÁ, Jana KLÁNOVÁ and Ivan HOLOUBEK. Photodegradation of Halobenzenes in Water Ice. \textit{Environmental Science and Pollution Research}. Landsberg, Germany: Ecomed, 2001, vol.~8, No~3, p.~195-200. ISSN~0944-1344.
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