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@inproceedings{366823, author = {Pinkas, Jiří and Verkade, J. G.}, address = {Reading, UK}, booktitle = {PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS}, keywords = {CRYSTAL-STRUCTURE; ORGANOMETALLIC PRECURSORS; THERMAL-DECOMPOSITION; GALLIUM;COMPLEXES; NITRIDE; ADDUCTS}, language = {eng}, location = {Reading, UK}, isbn = {0308-664X}, pages = {333-337}, publisher = {GORDON BREACH SCI PUBL LTD, READING}, title = {Novel Aluminum and Gallium Atrane Structures and Reactivities}, year = {1994} }
TY - JOUR ID - 366823 AU - Pinkas, Jiří - Verkade, J. G. PY - 1994 TI - Novel Aluminum and Gallium Atrane Structures and Reactivities VL - 93, 1-4 PB - GORDON BREACH SCI PUBL LTD, READING CY - Reading, UK SN - 0308664X KW - CRYSTAL-STRUCTURE KW - ORGANOMETALLIC PRECURSORS KW - THERMAL-DECOMPOSITION KW - GALLIUM;COMPLEXES KW - NITRIDE KW - ADDUCTS N2 - New monomeric azaaluminatranes and gallatranes of the type M(RNCH(2)CH(2))(3)N (M = Al, R = Me(3)Si (8) or tert-BuMe(2)Si (9); M = Ga, R = Me(3)Si (10) or tert-BuMe(2)Si (11)) have been prepared, with characterization including a molecular structure determination in the case of 8. Three dimeric azaalumatranes, namely, [Al(MeNCH(2)CH(2))(3)N](2) (12) and [Al(Me(3)SiNCH(2)CH(2))(2)(HNCH2CH2)N](2) (13) and [Ga(MeNCH(2)CH(2))(3)N](2) (14) have also been structurally characterized and all three compounds feature a central (M-N)(2) four-membered ring with a cis configuration of the nitrogen substituents. Some of the reaction chemistry of these systems is outlined and Al-27 NMR trends as a function of coordination number and geometry are discussed. ER -
PINKAS, Jiří and J. G. VERKADE. Novel Aluminum and Gallium Atrane Structures and Reactivities. In \textit{PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS}. Reading, UK: GORDON BREACH SCI PUBL LTD, READING, 1994, p.~333-337. 93, 1-4. ISBN~0308-664X.
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