POTÁČEK, Milan and Jiří POSPÍŠIL. Intramolecular 1,3-Dipolar Cycloaddition Initiated by Microwaves. In Proceedings - 18th International Congres of Heterocyclic Chemistry. 1st ed. Yokohama: Graduate School of Pharmaceutical Sciences, University of Tokyo, 2001, p. 478.
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Basic information
Original name Intramolecular 1,3-Dipolar Cycloaddition Initiated by Microwaves
Authors POTÁČEK, Milan and Jiří POSPÍŠIL.
Edition 1. vyd. Yokohama, Proceedings - 18th International Congres of Heterocyclic Chemistry, p. 478-478, 2001.
Publisher Graduate School of Pharmaceutical Sciences, University of Tokyo
Other information
Original language English
Type of outcome Proceedings paper
Field of Study 10401 Organic chemistry
Country of publisher Japan
Confidentiality degree is not subject to a state or trade secret
RIV identification code RIV/00216224:14310/01:00004360
Organization unit Faculty of Science
Keywords in English Microwaves; 1;3-Dipolar Cycloaddition; Intramolecular cycloaddition
Tags 1, 3-dipolar cycloaddition, intramolecular cycloaddition, microwaves
Changed by Changed by: prof. RNDr. Milan Potáček, CSc., učo 638. Changed: 2/10/2002 12:17.
Abstract
In our experiments we concentrated on application of azomethine ylides stabilized by carbonyl in intramolecular cycloaddition reaction under microwave irradiation. Thus, aromatic aldehydes with gama-double bond in ortho-position bound chain afforded in the presence of secondary amine fused heterocyclic compounds.We tried to compare some of the known reactions carried at classical heating with newly substituted substrates in order to follow influence of substitution upon the reaction. Application of microwaves represents a new field of reaction conditions improvement as well as a way of compounds preparation in higher yield and shorter time comparatively with classical conditions and sometimes is very close to so called "green chemistry" when working without solvents.
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MSM 143100011, plan (intention)Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles
PZ-CH/25, research and development projectName: Nový způsob přípravy adamantanu a jeho vybraných derivátů.
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