Detailed Information on Publication Record
2001
Intramolecular 1,3-Dipolar Cycloaddition Initiated by Microwaves
POTÁČEK, Milan and Jiří POSPÍŠILBasic information
Original name
Intramolecular 1,3-Dipolar Cycloaddition Initiated by Microwaves
Authors
POTÁČEK, Milan and Jiří POSPÍŠIL
Edition
1. vyd. Yokohama, Proceedings - 18th International Congres of Heterocyclic Chemistry, p. 478-478, 2001
Publisher
Graduate School of Pharmaceutical Sciences, University of Tokyo
Other information
Language
English
Type of outcome
Stať ve sborníku
Field of Study
10401 Organic chemistry
Country of publisher
Japan
Confidentiality degree
není předmětem státního či obchodního tajemství
RIV identification code
RIV/00216224:14310/01:00004360
Organization unit
Faculty of Science
Keywords in English
Microwaves; 1;3-Dipolar Cycloaddition; Intramolecular cycloaddition
Změněno: 2/10/2002 12:17, prof. RNDr. Milan Potáček, CSc.
Abstract
V originále
In our experiments we concentrated on application of azomethine ylides stabilized by carbonyl in intramolecular cycloaddition reaction under microwave irradiation. Thus, aromatic aldehydes with gama-double bond in ortho-position bound chain afforded in the presence of secondary amine fused heterocyclic compounds.We tried to compare some of the known reactions carried at classical heating with newly substituted substrates in order to follow influence of substitution upon the reaction. Application of microwaves represents a new field of reaction conditions improvement as well as a way of compounds preparation in higher yield and shorter time comparatively with classical conditions and sometimes is very close to so called "green chemistry" when working without solvents.
Links
| MSM 143100011, plan (intention) |
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| PZ-CH/25, research and development project |
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