Molecular Photochemical Thermometers. Investigation of
Microwave Superheating Effects By Temperature Dependent
Photochemical Processes

J 2001

Molecular Photochemical Thermometers. Investigation of Microwave Superheating Effects By Temperature Dependent Photochemical Processes

KLÁN, Petr, Jaromír LITERÁK and Stanislav RELICH

Basic information

Original name

Molecular Photochemical Thermometers. Investigation of Microwave Superheating Effects By Temperature Dependent Photochemical Processes

Authors

KLÁN, Petr (203 Czech Republic, guarantor), Jaromír LITERÁK (203 Czech Republic) and Stanislav RELICH (203 Czech Republic)

Edition

Journal of Photochemistry and Photobiology A: Chemistry, Amsterdam, The Netherlands, Elsevier Science, 2001, 1010-6030

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10401 Organic chemistry

Country of publisher

Netherlands

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 1.038

RIV identification code

RIV/00216224:14310/01:00004367

Organization unit

Faculty of Science

Keywords (in Czech)

fotochemie; mikrovlny

Keywords in English

photochemistry; microwave

Abstract

V originále

The first study of temperature dependent photochemical reactions in the microwave field is reported. Two different photochemical processes, temperature dependent solvent effects in the Norrish type II reaction and the photo-Fries reaction, were investigated under various thermal conditions including microwave heating. The former process exhibited a linear and reliable temperature dependence which served for the estimation of the microwave superheating effects in four different solvents. Their magnitudes were in a perfect agreement with the measured temperature enhancements. Thus, this photochemical system is proposed as a reliable molecular photochemical thermometer. The latter photochemical reaction studied showed a non-linear temperature dependence. All chemical changes in the microwave field were rationalized as a consequence of thermal effects.

Links

MSM 143100005, plan (intention)

Name: Strukturně-funkční vztahy biomolekul a jejich role v metabolismu

Investor: Ministry of Education, Youth and Sports of the CR, Biomolecular Structure-function Relationships and their role in the Metabolism

Citovat

KLÁN, Petr, Jaromír LITERÁK and Stanislav RELICH. Molecular Photochemical Thermometers. Investigation of Microwave Superheating Effects By Temperature Dependent Photochemical Processes. Journal of Photochemistry and Photobiology A: Chemistry. Amsterdam, The Netherlands: Elsevier Science, 2001, vol. 143, No 1, p. 49-57. ISSN 1010-6030.

@article{366951,
   author = {Klán, Petr and Literák, Jaromír and Relich, Stanislav},
   article_location = {Amsterdam, The Netherlands},
   article_number = {1},
   keywords = {photochemistry; microwave},
   language = {eng},
   issn = {1010-6030},
   journal = {Journal of Photochemistry and Photobiology A: Chemistry},
   title = {Molecular Photochemical Thermometers. Investigation of Microwave Superheating Effects By Temperature Dependent Photochemical Processes},
   volume = {143},
   year = {2001}
}

TY  - JOUR
ID  - 366951
AU  - Klán, Petr - Literák, Jaromír - Relich, Stanislav
PY  - 2001
TI  - Molecular Photochemical Thermometers. Investigation of Microwave Superheating Effects By Temperature Dependent Photochemical Processes
JF  - Journal of Photochemistry and Photobiology A: Chemistry
VL  - 143
IS  - 1
SP  - 49
EP  - 49
PB  - Elsevier Science
SN  - 10106030
KW  - photochemistry
KW  - microwave
N2  - The first study of temperature dependent photochemical reactions in the microwave field is reported. Two different photochemical processes, temperature dependent solvent effects in the Norrish type II reaction and the photo-Fries reaction, were investigated under various thermal conditions including microwave heating. The former process exhibited a linear and reliable temperature dependence which served for the estimation of the microwave superheating effects in four different solvents. Their magnitudes were in a perfect agreement with the measured temperature enhancements. Thus, this photochemical system is proposed as a reliable molecular photochemical thermometer. The latter photochemical reaction studied showed a non-linear temperature dependence. All chemical changes in the microwave field were rationalized as a consequence of thermal effects.
ER  -

KLÁN, Petr, Jaromír LITERÁK and Stanislav RELICH. Molecular Photochemical Thermometers. Investigation of Microwave Superheating Effects By Temperature Dependent Photochemical Processes. \textit{Journal of Photochemistry and Photobiology A: Chemistry}. Amsterdam, The Netherlands: Elsevier Science, 2001, vol.~143, No~1, p.~49-57. ISSN~1010-6030.

Detailed Information on Publication Record