LUBAL, Přemysl, Tomáš GODULA and Josef HAVEL. The Complexation of Palladium(II) with Chloroacetate. Chemical Papers. Bratislava: SAV, 2001, vol. 55, No 3, p. 157-161. ISSN 0366-6352.
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Basic information
Original name The Complexation of Palladium(II) with Chloroacetate
Authors LUBAL, Přemysl, Tomáš GODULA and Josef HAVEL.
Edition Chemical Papers, Bratislava, SAV, 2001, 0366-6352.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10406 Analytical chemistry
Country of publisher Slovakia
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 0.349
RIV identification code RIV/00216224:14310/01:00004482
Organization unit Faculty of Science
Changed by Changed by: prof. RNDr. Přemysl Lubal, Ph.D., učo 1271. Changed: 24/10/2001 13:08.
Abstract
The complexation of palladium(II) by chloroacetate was studied by spectrophotometry in 1.00 M-(Na,H)ClO4 at (25.0 +/- 0.2) 0 C. The experimental data were treated numerically by OPIUM program. The stability constant log Beta(PdL) =3.309 +/- 0.011 and spectra of individual species were calculated. The calculated stability constant is in good agreement with the value predicted by LFER approach (3.48 +/- 0.13). The thermodynamic parameters of complexation reaction, delta H = (-10.7 +/- 0.7) kJ mol-1 and delta S = -26.7 +/- 42.1) J K-1 mol-1, were also estimated by weighted linear least-squares procedure from the dependence of stability constant on temperature in the region 25-44 0 C.
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MSM 143100011, plan (intention)Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles
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