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@article{370864, author = {Lubal, Přemysl and Godula, Tomáš and Havel, Josef}, article_location = {Bratislava}, article_number = {3}, language = {eng}, issn = {0366-6352}, journal = {Chemical Papers}, title = {The Complexation of Palladium(II) with Chloroacetate}, volume = {55}, year = {2001} }
TY - JOUR ID - 370864 AU - Lubal, Přemysl - Godula, Tomáš - Havel, Josef PY - 2001 TI - The Complexation of Palladium(II) with Chloroacetate JF - Chemical Papers VL - 55 IS - 3 SP - 157 EP - 157 PB - SAV SN - 03666352 N2 - The complexation of palladium(II) by chloroacetate was studied by spectrophotometry in 1.00 M-(Na,H)ClO4 at (25.0 +/- 0.2) 0 C. The experimental data were treated numerically by OPIUM program. The stability constant log Beta(PdL) =3.309 +/- 0.011 and spectra of individual species were calculated. The calculated stability constant is in good agreement with the value predicted by LFER approach (3.48 +/- 0.13). The thermodynamic parameters of complexation reaction, delta H = (-10.7 +/- 0.7) kJ mol-1 and delta S = -26.7 +/- 42.1) J K-1 mol-1, were also estimated by weighted linear least-squares procedure from the dependence of stability constant on temperature in the region 25-44 0 C. ER -
LUBAL, Přemysl, Tomáš GODULA and Josef HAVEL. The Complexation of Palladium(II) with Chloroacetate. \textit{Chemical Papers}. Bratislava: SAV, 2001, vol.~55, No~3, p.~157-161. ISSN~0366-6352.
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