On the reaction of chlorodithiophosphoric acid
pyridiniumbetaine with polyfunctional nucleophiles; Part II.
Reaction with thiosemicarbazide derivatives.

J 2001

On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives.

JANČA, Michal, Marek NEČAS, Zdirad ŽÁK and Jiří PŘÍHODA

Basic information

Original name

On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives.

Authors

JANČA, Michal (203 Czech Republic), Marek NEČAS (203 Czech Republic), Zdirad ŽÁK (203 Czech Republic) and Jiří PŘÍHODA (203 Czech Republic, guarantor)

Edition

Polyhedron, Velká Británie, 2001, 0277-5387

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 1.200

RIV identification code

RIV/00216224:14310/01:00004581

Organization unit

Faculty of Science

UT WoS

000172076300008

Keywords in English

four-membered heterocycle; five-membered heterocycle; diazadiphosphetidine; chlorodithiophosphoric acid pyridiniumbetaine

Abstract

V originále

Chlorodithiophosphoric acid pyridiniumbetaine, PyPS2Cl (I), reacts with thiosemicarbazide derivatives (RNH)(H2N-Me)CS, R= iso-propyl, tert.-butyl, in acetonitrile in absence of any HCl-acceptor to new compounds with five-membered heterocycle, i.e. 5-iso-propylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (II) or 5-tert.-butylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (III). The triethylammonium salt of 1,3-bis-(N-methyl-N'-tert.-butyl-thioureido)-2,4-disulfido-2,4-dithioxo-1,3-diaza-2?5,4?5-diphosphetidine (IV) is formed when the reaction is carried out in the presence of triethylamine. The prepared compounds were characterised by 31P-NMR, FT-IR spectroscopies, mass spectrometry, and the molecular structures of II, III, and IV were determined by X-ray crystallography.

Links

MSM 143100011, plan (intention)

Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles

Citovat

JANČA, Michal, Marek NEČAS, Zdirad ŽÁK and Jiří PŘÍHODA. On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives. Polyhedron. Velká Británie, 2001, vol. 2001, No 20, p. 2823-2828. ISSN 0277-5387.

@article{372971,
   author = {Janča, Michal and Nečas, Marek and Žák, Zdirad and Příhoda, Jiří},
   article_location = {Velká Británie},
   article_number = {20},
   keywords = {four-membered heterocycle; five-membered heterocycle; diazadiphosphetidine; chlorodithiophosphoric acid pyridiniumbetaine},
   language = {eng},
   issn = {0277-5387},
   journal = {Polyhedron},
   title = {On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives.},
   volume = {2001},
   year = {2001}
}

TY  - JOUR
ID  - 372971
AU  - Janča, Michal - Nečas, Marek - Žák, Zdirad - Příhoda, Jiří
PY  - 2001
TI  - On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives.
JF  - Polyhedron
VL  - 2001
IS  - 20
SP  - 2823
EP  - 2823
SN  - 02775387
KW  - four-membered heterocycle
KW  - five-membered heterocycle
KW  - diazadiphosphetidine
KW  - chlorodithiophosphoric acid pyridiniumbetaine
N2  - Chlorodithiophosphoric acid pyridiniumbetaine, PyPS2Cl (I), reacts with thiosemicarbazide derivatives (RNH)(H2N-Me)CS, R= iso-propyl, tert.-butyl, in acetonitrile in absence of any HCl-acceptor to new compounds with five-membered heterocycle, i.e. 5-iso-propylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (II) or 5-tert.-butylamino-4-methyl-2-sulfido-2-thioxo-1,3,4,2?5-thiadiazaphospholan-5-onium (III). The triethylammonium salt of 1,3-bis-(N-methyl-N'-tert.-butyl-thioureido)-2,4-disulfido-2,4-dithioxo-1,3-diaza-2?5,4?5-diphosphetidine (IV) is formed when the reaction is carried out in the presence of triethylamine. The prepared compounds were characterised by 31P-NMR, FT-IR spectroscopies, mass spectrometry, and the molecular structures of II, III, and IV were determined by X-ray crystallography.
ER  -

JANČA, Michal, Marek NEČAS, Zdirad ŽÁK and Jiří PŘÍHODA. On the reaction of chlorodithiophosphoric acid pyridiniumbetaine with polyfunctional nucleophiles; Part II. Reaction with thiosemicarbazide derivatives. \textit{Polyhedron}. Velká Británie, 2001, vol.~2001, No~20, p.~2823-2828. ISSN~0277-5387.

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