Detailed Information on Publication Record
2001
Measurement of small scalar and resiudal dipolar couplings in purine and pyrimidine bases
ŽÍDEK, Lukáš, Haihong WU, Juli FEIGON and Vladimír SKLENÁŘBasic information
Original name
Measurement of small scalar and resiudal dipolar couplings in purine and pyrimidine bases
Authors
ŽÍDEK, Lukáš (203 Czech Republic), Haihong WU, Juli FEIGON and Vladimír SKLENÁŘ (203 Czech Republic, guarantor)
Edition
Journal of Biomolecular NMR, Dordrecht, Kluwer/Escom, 2001, 0925-2738
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10403 Physical chemistry
Country of publisher
Netherlands
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 4.636
RIV identification code
RIV/00216224:14310/01:00004651
Organization unit
Faculty of Science
Keywords in English
NMR methods; nucleic acid bases; residual dipolar couplings; spin-state-selective filter
Změněno: 20/6/2008 12:40, prof. RNDr. Vladimír Sklenář, DrSc.
Abstract
V originále
A suite of spin-state-selective excitation (S3E) NMR experiments for the measurements of small one-bond (13C - 13C, 13C - 15N) and two-bond (1H - 13C, 1H - 15N) coupling constants in 13C, 15N labeled purine and pyrimidine bases is presented. The incorporation of band-selective shaped pulses, elimination of the cross talk between á and â sub-spectra, and accuracy and precision of the proposed approach are discussed. Merits of using S3 E rather than á/â-half-filter are demonstrated using results obtained on isotopicaly labeled DNA oligonucleotides.
Links
| LN00A016, research and development project |
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