| TRÁVNÍČEK, Martin, Milan POTÁČEK and Albrecht MANNSCHRECK. Stereochemistry of 1,3-dipolar Cycloaddition Reaction of Azomethine Ylides Derived from N-alkyl-N-(4-toluenesulfonyl)carbamoylmethyl phenanthridinium with Olefinic Dipolarophiles. Heterocyclic Communications. London: Freund Publishing House, 2001, vol. 2001, No 3, p. 213-222. ISSN 0793-0283. |
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@article{377771,
author = {Trávníček, Martin and Potáček, Milan and Mannschreck, Albrecht},
article_location = {London},
article_number = {3},
keywords = {Stereochemistry; 1;3-dipolar cycloaddition; azomethine ylide; carbamoylmethylphenanthridinium; olefinic dipolarophiles},
language = {eng},
issn = {0793-0283},
journal = {Heterocyclic Communications},
title = {Stereochemistry of 1,3-dipolar Cycloaddition Reaction of Azomethine Ylides Derived from N-alkyl-N-(4-toluenesulfonyl)carbamoylmethyl phenanthridinium with Olefinic Dipolarophiles.},
volume = {2001},
year = {2001}
}
TY - JOUR
ID - 377771
AU - Trávníček, Martin - Potáček, Milan - Mannschreck, Albrecht
PY - 2001
TI - Stereochemistry of 1,3-dipolar Cycloaddition Reaction of Azomethine Ylides Derived from N-alkyl-N-(4-toluenesulfonyl)carbamoylmethyl phenanthridinium with Olefinic Dipolarophiles.
JF - Heterocyclic Communications
VL - 2001
IS - 3
SP - 213
EP - 213
PB - Freund Publishing House
SN - 07930283
KW - Stereochemistry
KW - 1;3-dipolar cycloaddition
KW - azomethine ylide
KW - carbamoylmethylphenanthridinium
KW - olefinic dipolarophiles
N2 - A series of prepared N-alkyl-N-(p-toluenesulfonyl) bromoacetamides afforded with phenanthridine quarternary phenanthridinium salts. These when treated with triethylamine in dichloromethane form azomethine ylides that undergo cyclization reaction with present activated olefinic double bond. This way pyrrolidino[1,2-f]phenanthridines can be obtained. Their stereochemistry was studied. Some of them were separated on non-racemic cellulose based sorbents with CD detection.
ER -
TRÁVNÍČEK, Martin, Milan POTÁČEK and Albrecht MANNSCHRECK. Stereochemistry of 1,3-dipolar Cycloaddition Reaction of Azomethine Ylides Derived from N-alkyl-N-(4-toluenesulfonyl)carbamoylmethyl phenanthridinium with Olefinic Dipolarophiles. \textit{Heterocyclic Communications}. London: Freund Publishing House, 2001, vol.~2001, No~3, p.~213-222. ISSN~0793-0283.
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