SLUKA, Radek and Miloš ČERNÍK. Syntéza fluorodi- a fluorotrifosforečnanů. (Synthesis of fluorodi- and fluorotriphosphates.). In Pokroky v anorganickej chémii. Sborník prispevkov. Modra-Piesok, Slovensko: KU Bratislava, 2000, p. 40-41.
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Basic information
Original name Syntéza fluorodi- a fluorotrifosforečnanů.
Name (in English) Synthesis of fluorodi- and fluorotriphosphates.
Authors SLUKA, Radek (203 Czech Republic) and Miloš ČERNÍK (203 Czech Republic, guarantor).
Edition Modra-Piesok, Slovensko, Pokroky v anorganickej chémii. Sborník prispevkov. p. 40-41, 2 pp. 2000.
Publisher KU Bratislava
Other information
Original language Czech
Type of outcome Proceedings paper
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher Slovakia
Confidentiality degree is not subject to a state or trade secret
RIV identification code RIV/00216224:14310/00:00006043
Organization unit Faculty of Science
Keywords in English Fluorodiphosphates; Fluorotriphosphates; Synthesis;NMR spectroscopy
Tags Fluorodiphosphates, Fluorotriphosphates, NMR Spectroscopy, synthesis
Changed by Changed by: RNDr. Miloš Černík, CSc., učo 2255. Changed: 29/5/2003 13:39.
Abstract
Prostřednictvím 19F a 31P NMR spektroskopie byla studována možnost syntézy nových typů fluorodi- a fluorotrifosforečnanů. Nový anion 1,1,2-trifluorodifosforečnanový byl získán substitucí atomu chloru v aniontu PO2ClF(-) skupinou -OP(O)F2.Podobně se zdařila syntéza dosud neznámého 1,1,3,3-tetrafluorotrifosforečnanu reakcí dichlorofosforečnanu s nadbytkem FP(O)OP(O)F2.
Abstract (in English)
The possibility of synthesis of new fluorodi- and fluorotriphosphate anions was studied by 19F and 31P NMR spectroscopy. A new 1,1,2-tri-fluorodiphosphate was obtained by the substitution of chlorine in the PO2ClF(-) anion by a -OP(O)F2 group. Similarly, the so far unknown 1,1,3,3-tetrafluorotriphosphate was synthesized by the reaction of dichlorophosphate with an excess of F2P(O)OP(O)F2.
Links
GA203/98/0676, research and development projectName: Krystalová struktura a vazebné poměry sloučenin nekovů V., VI. a VII. grupy periodického systému
Investor: Czech Science Foundation, Crystal structures and bonding in non-metal compounds of the V., VI. , and VII. group of the periodic systém
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