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@inproceedings{385199,
author = {Žák, Zdirad and Černík, Miloš},
address = {Lisboa},
booktitle = {17th European Crystallographic Meeting. Book of Abstracts.},
keywords = {Bis(difluorooxoiodonium)Selenate; Synthesis; Crystal structure},
language = {eng},
location = {Lisboa},
pages = {159-159},
publisher = {IUCr},
title = {Bis(difluorooxoiodonium)Selenate.},
year = {1997}
}
TY - JOUR
ID - 385199
AU - Žák, Zdirad - Černík, Miloš
PY - 1997
TI - Bis(difluorooxoiodonium)Selenate.
PB - IUCr
CY - Lisboa
KW - Bis(difluorooxoiodonium)Selenate
KW - Synthesis
KW - Crystal structure
N2 - Bis(difluorooxoiodonium)Selenate.The title compound has been prepared by reaction of iodine pentafluoride with (SeO3)4. Its X-ray single crystal structure analysis revealed a rather covalent than ionic structure with an F2(O)IOSeO2OI(O)F2 molecule. Due to unsaturated coordination of I(V) atoms, every molecule is linked via 4 relatively strong SeO...I interactions to its two nearest neighbours forming corrugated eight-membered rings. These rings are joined by common Se(VI) spiroatoms into infinite chains.
ER -
ŽÁK, Zdirad and Miloš ČERNÍK. Bis(difluorooxoiodonium)Selenate. In \textit{17th European Crystallographic Meeting. Book of Abstracts.}. Lisboa: IUCr, 1997, p.~159-159.
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