| RAKOVSKÝ, E., L. ŽURKOVÁ a Jaromír MAREK. Synthesis, crystal structure, and IR spectroscopic characterization of 1,6-hexanediammonium dihydrogendecavanadate. Monatshefte fuer Chemie, Chemical Monthly. Wien: Springer-Verlag, 2002, roč. 133, č. 3, s. 177-183. ISSN 0026-9247. |
Další formáty:
BibTeX
LaTeX
RIS
@article{400913,
author = {Rakovský, E. and Žurková, L. and Marek, Jaromír},
article_location = {Wien},
article_number = {3},
keywords = {THERMAL-BEHAVIOR; DECAVANADATES; PROTONATION; IR spectroscopy; X-Ray structure},
language = {eng},
issn = {0026-9247},
journal = {Monatshefte fuer Chemie, Chemical Monthly},
title = {Synthesis, crystal structure, and IR spectroscopic characterization of 1,6-hexanediammonium dihydrogendecavanadate},
volume = {133},
year = {2002}
}
TY - JOUR
ID - 400913
AU - Rakovský, E. - Žurková, L. - Marek, Jaromír
PY - 2002
TI - Synthesis, crystal structure, and IR spectroscopic characterization of 1,6-hexanediammonium dihydrogendecavanadate
JF - Monatshefte fuer Chemie, Chemical Monthly
VL - 133
IS - 3
SP - 177
EP - 177
PB - Springer-Verlag
SN - 00269247
KW - THERMAL-BEHAVIOR
KW - DECAVANADATES
KW - PROTONATION
KW - IR spectroscopy
KW - X-Ray structure
N2 - Anhydrous 1,6-hexanediammonium dihydrogendecavanadate ((HdaH(2))(2)H2V10O28, 1) was prepared by reaction Of V2O5 with 1,6-hexanediamine in aqueous solution. The crystal structure of I was determined, and the proton positions in the H2V10O284- anion were calculated by the bond length/bond number method. The protons are bound to the centrosymmetrically oriented mu-OV3 groups of the decavanadate anion. Based on the analysis of IR spectra of 1 prepared from H2O and D2O, the absorption band at 871 cm(-1) can be attributed to delta(V-O-b-H) vibrations
ER -
RAKOVSKÝ, E., L. ŽURKOVÁ a Jaromír MAREK. Synthesis, crystal structure, and IR spectroscopic characterization of 1,6-hexanediammonium dihydrogendecavanadate. \textit{Monatshefte fuer Chemie, Chemical Monthly}. Wien: Springer-Verlag, 2002, roč.~133, č.~3, s.~177-183. ISSN~0026-9247.
|
