D 2002

CYANOCOMPLEXES WITH MULTI-N-DONOR LIGANDS

ČERNÁK, J., J. PAHÁROVÁ, Zdirad ŽÁK and Jaromír MAREK

Basic information

Original name

CYANOCOMPLEXES WITH MULTI-N-DONOR LIGANDS

Authors

ČERNÁK, J. (703 Slovakia), J. PAHÁROVÁ (703 Slovakia), Zdirad ŽÁK (203 Czech Republic, guarantor) and Jaromír MAREK (203 Czech Republic)

Edition

WASHINGTON, 223rd ACS (=American Chemical Society) National Meeting, p. 063-63, 2002

Publisher

American Chemical Society

Other information

Language

English

Type of outcome

Stať ve sborníku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

RIV identification code

RIV/00216224:14310/02:00006304

Organization unit

Faculty of Science

ISBN

ISSN:0065-7727

UT WoS

000176296800064

Keywords in English

structure; cyanocomplex
Změněno: 21/5/2003 10:24, doc. RNDr. Jaromír Marek, Ph.D.

Abstract

V originále

Cyanocomplexes containing bridging cyano ligands are attractive group of compounds as they may serve as models for the study of various physical phenomena associated with magnetism.Systems with various dimensionalities can be constructed using the 'brick and mortar' method. The dimensionality of the formed system can be controlled by a suitable choice of N-donor ligands coordinated to the cationic central atom (brick).The linking of the complex cations is made possible by the cyanocomplex anions (mortar). In search for new low-dimensional systems we have used the multi-N donor ligands dien (dien=N-(2-aminoethyl)-1,2-etylenediamine)and aepn (aepn=N-(2-aminoethyl)- 1,3-propanediamine). Several new tetracyanonickellate compounds were prepared and characterized by X-ray diffraction,and the resulting materials include oligonuclear and low-dimensional structures.

Links

MSM 143100011, plan (intention)
Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles