Detailed Information on Publication Record
2002
CYANOCOMPLEXES WITH MULTI-N-DONOR LIGANDS
ČERNÁK, J., J. PAHÁROVÁ, Zdirad ŽÁK and Jaromír MAREKBasic information
Original name
CYANOCOMPLEXES WITH MULTI-N-DONOR LIGANDS
Authors
ČERNÁK, J. (703 Slovakia), J. PAHÁROVÁ (703 Slovakia), Zdirad ŽÁK (203 Czech Republic, guarantor) and Jaromír MAREK (203 Czech Republic)
Edition
WASHINGTON, 223rd ACS (=American Chemical Society) National Meeting, p. 063-63, 2002
Publisher
American Chemical Society
Other information
Language
English
Type of outcome
Stať ve sborníku
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
United States of America
Confidentiality degree
není předmětem státního či obchodního tajemství
RIV identification code
RIV/00216224:14310/02:00006304
Organization unit
Faculty of Science
ISBN
ISSN:0065-7727
UT WoS
000176296800064
Keywords in English
structure; cyanocomplex
Tags
Změněno: 21/5/2003 10:24, doc. RNDr. Jaromír Marek, Ph.D.
Abstract
V originále
Cyanocomplexes containing bridging cyano ligands are attractive group of compounds as they may serve as models for the study of various physical phenomena associated with magnetism.Systems with various dimensionalities can be constructed using the 'brick and mortar' method. The dimensionality of the formed system can be controlled by a suitable choice of N-donor ligands coordinated to the cationic central atom (brick).The linking of the complex cations is made possible by the cyanocomplex anions (mortar). In search for new low-dimensional systems we have used the multi-N donor ligands dien (dien=N-(2-aminoethyl)-1,2-etylenediamine)and aepn (aepn=N-(2-aminoethyl)- 1,3-propanediamine). Several new tetracyanonickellate compounds were prepared and characterized by X-ray diffraction,and the resulting materials include oligonuclear and low-dimensional structures.
Links
MSM 143100011, plan (intention) |
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